Effects of thermal treatment and nucleating agents on crystallinity, toughness, and stiffness of PLA/PCL blends
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F22%3A00550856" target="_blank" >RIV/61389013:_____/22:00550856 - isvavai.cz</a>
Výsledek na webu
<a href="http://www.expresspolymlett.com/issue.php?y=2022&n=3" target="_blank" >http://www.expresspolymlett.com/issue.php?y=2022&n=3</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3144/expresspolymlett.2022.18" target="_blank" >10.3144/expresspolymlett.2022.18</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Effects of thermal treatment and nucleating agents on crystallinity, toughness, and stiffness of PLA/PCL blends
Popis výsledku v původním jazyce
The effects of the thermal treatment and nucleating agents on the morphology, crystallinity, and mechanical properties of poly(lactic acid)/poly(ε-caprolactone) (PLA/PCL) blends were studied in order to obtain PLA/PCL blends with both high stiffness and toughness. The standard thermal treatment of the melt-mixed blends (a compression molding without annealing) resulted in the systems with optimized morphology (at PLA/PCL ratio 80/20) and very high toughness (ca 16×higher with respect to neat PLA), but the stiffness at elevated temperatures (above Tg of PLA at 65 °C) was low due to the low crystallinity of the PLA matrix (<10%). The compression molding with annealing at 110 °C could increase the crystallinity of PLA (up to ~40%), but the toughness decreased steeply due to morphological changes (a coalescence of PCL particles associated with the structure coarsening). The lowering of the annealing temperature (to 80 °C) and addition of the PLA nucleating agent (1 wt% of talc) led to the blends showing both high toughness (9× with respect to neat PLA) and crystallinity (~35%). Dynamic mechanical analysis evidenced that the higher PLA crystallinity improved the storage modulus at temperatures >60 °C by ca two orders of magnitude. The achieved combination of the PLA/PCL toughness and stiffness was one of the highest, according to the available literature.
Název v anglickém jazyce
Effects of thermal treatment and nucleating agents on crystallinity, toughness, and stiffness of PLA/PCL blends
Popis výsledku anglicky
The effects of the thermal treatment and nucleating agents on the morphology, crystallinity, and mechanical properties of poly(lactic acid)/poly(ε-caprolactone) (PLA/PCL) blends were studied in order to obtain PLA/PCL blends with both high stiffness and toughness. The standard thermal treatment of the melt-mixed blends (a compression molding without annealing) resulted in the systems with optimized morphology (at PLA/PCL ratio 80/20) and very high toughness (ca 16×higher with respect to neat PLA), but the stiffness at elevated temperatures (above Tg of PLA at 65 °C) was low due to the low crystallinity of the PLA matrix (<10%). The compression molding with annealing at 110 °C could increase the crystallinity of PLA (up to ~40%), but the toughness decreased steeply due to morphological changes (a coalescence of PCL particles associated with the structure coarsening). The lowering of the annealing temperature (to 80 °C) and addition of the PLA nucleating agent (1 wt% of talc) led to the blends showing both high toughness (9× with respect to neat PLA) and crystallinity (~35%). Dynamic mechanical analysis evidenced that the higher PLA crystallinity improved the storage modulus at temperatures >60 °C by ca two orders of magnitude. The achieved combination of the PLA/PCL toughness and stiffness was one of the highest, according to the available literature.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10404 - Polymer science
Návaznosti výsledku
Projekt
<a href="/cs/project/NU21-06-00084" target="_blank" >NU21-06-00084: Vliv typu polyetylénu UHMWPE na životnost náhrady kolenního kloubu a souvislost s designem kloubních ploch implantátu</a><br>
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Express Polymer Letters
ISSN
1788-618X
e-ISSN
1788-618X
Svazek periodika
16
Číslo periodika v rámci svazku
3
Stát vydavatele periodika
HU - Maďarsko
Počet stran výsledku
13
Strana od-do
221-233
Kód UT WoS článku
000752462200002
EID výsledku v databázi Scopus
2-s2.0-85125891967