Monitoring of morphology and properties during preparation of PCL/PLA microfibrillar composites with organophilic montmorillonite

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F20%3A00525258" target="_blank" >RIV/61389013:_____/20:00525258 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.frontiersin.org/articles/10.3389/fmats.2020.00188/full" target="_blank" >https://www.frontiersin.org/articles/10.3389/fmats.2020.00188/full</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3389/fmats.2020.00188" target="_blank" >10.3389/fmats.2020.00188</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Monitoring of morphology and properties during preparation of PCL/PLA microfibrillar composites with organophilic montmorillonite

Popis výsledku v původním jazyce

Biodegradable microfibrillar composites PCL/PLA/C15, where PCL is poly(ε-caprolactone), PLA is poly(lactic acid), and C15 is organophilic montmorillonite, have been prepared. Microindentation hardness testing was employed in monitoring the gradual improvement of PCL stiffness due to PLA addition, C15 addition, flow-induced orientation, and changing crystallinity throughout the whole preparation process. Neat PCL after extrusion and injection molding was quite soft, but the stiffness of the material increased after melt-blending with 20 wt.% of PLA, after the addition of 2 wt.% of C15, and after the preparation of the final microfibrillar composite. The indentation modulus and indentation hardness of all intermediate products and the final PCL/PLA/C15 microfibrillar composite were associated not only with the composition and morphology but also with the crystallinity of both components. The modulus of the final PCL/PLA/C15 composite was almost two times higher in comparison with the original PCL matrix.

Název v anglickém jazyce

Monitoring of morphology and properties during preparation of PCL/PLA microfibrillar composites with organophilic montmorillonite

Popis výsledku anglicky

Biodegradable microfibrillar composites PCL/PLA/C15, where PCL is poly(ε-caprolactone), PLA is poly(lactic acid), and C15 is organophilic montmorillonite, have been prepared. Microindentation hardness testing was employed in monitoring the gradual improvement of PCL stiffness due to PLA addition, C15 addition, flow-induced orientation, and changing crystallinity throughout the whole preparation process. Neat PCL after extrusion and injection molding was quite soft, but the stiffness of the material increased after melt-blending with 20 wt.% of PLA, after the addition of 2 wt.% of C15, and after the preparation of the final microfibrillar composite. The indentation modulus and indentation hardness of all intermediate products and the final PCL/PLA/C15 microfibrillar composite were associated not only with the composition and morphology but also with the crystallinity of both components. The modulus of the final PCL/PLA/C15 composite was almost two times higher in comparison with the original PCL matrix.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Frontiers in Materials

ISSN

2296-8016

e-ISSN

—

Svazek periodika

7

Číslo periodika v rámci svazku

25 June

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

16

Strana od-do

1-16

Kód UT WoS článku

000549174800001

EID výsledku v databázi Scopus

2-s2.0-85087740560