alpha-Fe2O3/TiO2 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F17%3AA1701LCY" target="_blank" >RIV/61988987:17310/17:A1701LCY - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989592:15310/17:73583536 RIV/61988987:17310/17:A2301LCY

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

alpha-Fe2O3/TiO2 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting

Popis výsledku v původním jazyce

We report the fabrication of 3D hierarchical hetero-nanostructures composed of thin alpha-Fe2O3 nanoflakes branched on TiO2 nanotubes. The novel alpha-Fe2O3/TiO2 hierarchical nanostructures, synthesized on FTO through a multi-step hydrothermal process, exhibit enhanced performances in photo-electrochemical water splitting and in the photocatalytic degradation of an organic dye, with respect to pure TiO2 nanotubes. An enhanced separation of photogenerated charge carriers is here proposed as the main factor for the observed photo-activities: electrons photogenerated in TiO2 are efficiently collected at FTO, while holes are transferred to the alpha-Fe2O3 nanobranches that serve as charge mediators to the electrolyte. The morphology of alpha-Fe2O3 that varies from ultrathin nanoflakes to nanorod/nanofiber structures depending on the Fe precursor concentration was shown to have a significant impact on the photo-induced activity of the alpha-Fe2O3/TiO2 composites. In particular, it is shown that for an optimized photo-electrochemical structure, a combination of critical factors should be achieved such as (i) TiO2 light absorption and photo-activation vs. alpha-Fe2O3-induced shadowing effect and (ii) the availability of free TiO2 surface vs. alpha-Fe2O3-coated surface. Finally, theoretical analysis, based on DFT calculations, confirmed the optical properties experimentally determined for the alpha-Fe2O3/TiO2 hierarchical nanostructures. We anticipate that this new multi-step hydrothermal process can be a blueprint for the design and development of other hierarchical heterogeneous metal oxide electrodes suitable for photo-electrochemical applications.

Název v anglickém jazyce

alpha-Fe2O3/TiO2 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting

Popis výsledku anglicky

We report the fabrication of 3D hierarchical hetero-nanostructures composed of thin alpha-Fe2O3 nanoflakes branched on TiO2 nanotubes. The novel alpha-Fe2O3/TiO2 hierarchical nanostructures, synthesized on FTO through a multi-step hydrothermal process, exhibit enhanced performances in photo-electrochemical water splitting and in the photocatalytic degradation of an organic dye, with respect to pure TiO2 nanotubes. An enhanced separation of photogenerated charge carriers is here proposed as the main factor for the observed photo-activities: electrons photogenerated in TiO2 are efficiently collected at FTO, while holes are transferred to the alpha-Fe2O3 nanobranches that serve as charge mediators to the electrolyte. The morphology of alpha-Fe2O3 that varies from ultrathin nanoflakes to nanorod/nanofiber structures depending on the Fe precursor concentration was shown to have a significant impact on the photo-induced activity of the alpha-Fe2O3/TiO2 composites. In particular, it is shown that for an optimized photo-electrochemical structure, a combination of critical factors should be achieved such as (i) TiO2 light absorption and photo-activation vs. alpha-Fe2O3-induced shadowing effect and (ii) the availability of free TiO2 surface vs. alpha-Fe2O3-coated surface. Finally, theoretical analysis, based on DFT calculations, confirmed the optical properties experimentally determined for the alpha-Fe2O3/TiO2 hierarchical nanostructures. We anticipate that this new multi-step hydrothermal process can be a blueprint for the design and development of other hierarchical heterogeneous metal oxide electrodes suitable for photo-electrochemical applications.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Nanoscale

ISSN

2040-3364

e-ISSN

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Svazek periodika

9

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

9

Strana od-do

134-142

Kód UT WoS článku

000391739300019

EID výsledku v databázi Scopus

2-s2.0-85007366503