alpha-Fe2O3/TiO2 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F17%3AA2301LCY" target="_blank" >RIV/61988987:17310/17:A2301LCY - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/61988987:17310/17:A1701LCY RIV/61989592:15310/17:73583536
Výsledek na webu
<a href="http://dx.doi.org/10.1039/C6NR06908H" target="_blank" >http://dx.doi.org/10.1039/C6NR06908H</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c6nr06908h" target="_blank" >10.1039/c6nr06908h</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
alpha-Fe2O3/TiO2 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting
Popis výsledku v původním jazyce
We report the fabrication of 3D hierarchical hetero-nanostructures composed of thin alpha-Fe2O3 nanoflakes branched on TiO2 nanotubes. The novel alpha-Fe2O3/TiO2 hierarchical nanostructures, synthesized on FTO through a multi-step hydrothermal process, exhibit enhanced performances in photo-electrochemical water splitting and in the photocatalytic degradation of an organic dye, with respect to pure TiO2 nanotubes. An enhanced separation of photogenerated charge carriers is here proposed as the main factor for the observed photo-activities: electrons photogenerated in TiO2 are efficiently collected at FTO, while holes are transferred to the alpha-Fe2O3 nanobranches that serve as charge mediators to the electrolyte. The morphology of alpha-Fe2O3 that varies from ultrathin nanoflakes to nanorod/nanofiber structures depending on the Fe precursor concentration was shown to have a significant impact on the photo-induced activity of the alpha-Fe2O3/TiO2 composites. In particular, it is shown that for an optimized photo-electrochemical structure, a combination of critical factors should be achieved such as (i) TiO2 light absorption and photo-activation vs. alpha-Fe2O3-induced shadowing effect and (ii) the availability of free TiO2 surface vs. alpha-Fe2O3-coated surface. Finally, theoretical analysis, based on DFT calculations, confirmed the optical properties experimentally determined for the alpha-Fe2O3/TiO2 hierarchical nanostructures. We anticipate that this new multi-step hydrothermal process can be a blueprint for the design and development of other hierarchical heterogeneous metal oxide electrodes suitable for photo-electrochemical applications.
Název v anglickém jazyce
alpha-Fe2O3/TiO2 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting
Popis výsledku anglicky
We report the fabrication of 3D hierarchical hetero-nanostructures composed of thin alpha-Fe2O3 nanoflakes branched on TiO2 nanotubes. The novel alpha-Fe2O3/TiO2 hierarchical nanostructures, synthesized on FTO through a multi-step hydrothermal process, exhibit enhanced performances in photo-electrochemical water splitting and in the photocatalytic degradation of an organic dye, with respect to pure TiO2 nanotubes. An enhanced separation of photogenerated charge carriers is here proposed as the main factor for the observed photo-activities: electrons photogenerated in TiO2 are efficiently collected at FTO, while holes are transferred to the alpha-Fe2O3 nanobranches that serve as charge mediators to the electrolyte. The morphology of alpha-Fe2O3 that varies from ultrathin nanoflakes to nanorod/nanofiber structures depending on the Fe precursor concentration was shown to have a significant impact on the photo-induced activity of the alpha-Fe2O3/TiO2 composites. In particular, it is shown that for an optimized photo-electrochemical structure, a combination of critical factors should be achieved such as (i) TiO2 light absorption and photo-activation vs. alpha-Fe2O3-induced shadowing effect and (ii) the availability of free TiO2 surface vs. alpha-Fe2O3-coated surface. Finally, theoretical analysis, based on DFT calculations, confirmed the optical properties experimentally determined for the alpha-Fe2O3/TiO2 hierarchical nanostructures. We anticipate that this new multi-step hydrothermal process can be a blueprint for the design and development of other hierarchical heterogeneous metal oxide electrodes suitable for photo-electrochemical applications.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Nanoscale
ISSN
2040-3364
e-ISSN
—
Svazek periodika
—
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
9
Strana od-do
134-142
Kód UT WoS článku
000391739300019
EID výsledku v databázi Scopus
2-s2.0-85007366503