Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F21%3A10248941" target="_blank" >RIV/61989100:27640/21:10248941 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989592:15310/20:73602465

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.202004560" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.202004560</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/adma.202004560" target="_blank" >10.1002/adma.202004560</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors

Popis výsledku v původním jazyce

In this work, the covalent attachment of an amine functionalized metal-organic framework (UiO-66-NH2 = Zr6O4(OH)(4)(bdc-NH2)(6); bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) (UiO-Universitetet i Oslo) to the basal-plane of carboxylate functionalized graphene (graphene acid = GA) via amide bonds is reported. The resultant GA@UiO-66-NH2 hybrid displayed a large specific surface area, hierarchical pores and an interconnected conductive network. The electrochemical characterizations demonstrated that the hybrid GA@UiO-66-NH2 acts as an effective charge storing material with a capacitance of up to 651 F g(-1), significantly higher than traditional graphene-based materials. The results suggest that the amide linkage plays a key role in the formation of a p-conjugated structure, which facilitates charge transfer and consequently offers good capacitance and cycling stability. Furthermore, to realize the practical feasibility, an asymmetric supercapacitor using a GA@UiO-66-NH2 positive electrode with Ti3C2TX MXene as the opposing electrode has been constructed. The cell is able to deliver a power density of up to 16 kW kg(-1) and an energy density of up to 73 Wh kg(-1), which are comparable to several commercial devices such as Pb-acid and Ni/MH batteries. Under an intermediate level of loading, the device retained 88% of its initial capacitance after 10 000 cycles.

Název v anglickém jazyce

Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors

Popis výsledku anglicky

In this work, the covalent attachment of an amine functionalized metal-organic framework (UiO-66-NH2 = Zr6O4(OH)(4)(bdc-NH2)(6); bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) (UiO-Universitetet i Oslo) to the basal-plane of carboxylate functionalized graphene (graphene acid = GA) via amide bonds is reported. The resultant GA@UiO-66-NH2 hybrid displayed a large specific surface area, hierarchical pores and an interconnected conductive network. The electrochemical characterizations demonstrated that the hybrid GA@UiO-66-NH2 acts as an effective charge storing material with a capacitance of up to 651 F g(-1), significantly higher than traditional graphene-based materials. The results suggest that the amide linkage plays a key role in the formation of a p-conjugated structure, which facilitates charge transfer and consequently offers good capacitance and cycling stability. Furthermore, to realize the practical feasibility, an asymmetric supercapacitor using a GA@UiO-66-NH2 positive electrode with Ti3C2TX MXene as the opposing electrode has been constructed. The cell is able to deliver a power density of up to 16 kW kg(-1) and an energy density of up to 73 Wh kg(-1), which are comparable to several commercial devices such as Pb-acid and Ni/MH batteries. Under an intermediate level of loading, the device retained 88% of its initial capacitance after 10 000 cycles.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10300 - Physical sciences

Projekt

<a href="/cs/project/GX19-27454X" target="_blank" >GX19-27454X: Ovlivnění elektronických vlastností organometalických molekul pomocí jejich nekovalentních interakcí s rozpouštědly, ligandy a 2D nanosystémy</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Advanced Materials

ISSN

0935-9648

e-ISSN

—

Svazek periodika

33

Číslo periodika v rámci svazku

4

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

2004560

Kód UT WoS článku

000596065400001

EID výsledku v databázi Scopus

2-s2.0-85097208378