Crystal structure, spectroscopic and magnetic properties, and antimicrobial activities of cobalt(II) 2-methylthionicotinate complexes with N -heterocyclic ligands

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F08%3A00009952" target="_blank" >RIV/61989592:15310/08:00009952 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Crystal structure, spectroscopic and magnetic properties, and antimicrobial activities of cobalt(II) 2-methylthionicotinate complexes with N -heterocyclic ligands

Popis výsledku v původním jazyce

Synthesis and characterization of 10 new 2-methylthionicotinate (2-MeSnic) Co(II) complexes, namely, [Co(2-MeSnic)2L2(H2O)2].nH2O (L is N,N-diethylnicotinamide-Et2nia, ethylnicotinate-Etnic, nicotinamide-nia, isonicotinamide-isonia, N-methylnicotinamide-N-Menia, furo[3,2-c]pyridine-fpy, 2,3-dimethylfuro[3,2-c]pyridine-Me2fpy or benzo[4,5]furo[3,2-c]pyridine-Bfp; n is 0, 1 or 2) as well as [Co(2-MeSnic)2L2] (L is ronicol-ron or 2-methylfuro[3,2-c]pyridine-Mefpy), are reported. The characterizations werebased on physico-chemical and spectroscopic methods. The crystal structure of one of the complexes has been determined. In the molecular complex [Co(2-MeSnic)2(Me2fpy)2(H2O)2], the Co(II) central atom, located at a symmetry centre, is octahedrally coordinated by an oxygen atom of the unidentate 2-MeSnic carboxyl group, the nitrogen atom of the pyridine ring of Me2fpy, a water molecule and the corresponding centrosymmetrically located atoms. Also, biological activity of the complexes agai

Název v anglickém jazyce

Crystal structure, spectroscopic and magnetic properties, and antimicrobial activities of cobalt(II) 2-methylthionicotinate complexes with N -heterocyclic ligands

Popis výsledku anglicky

Synthesis and characterization of 10 new 2-methylthionicotinate (2-MeSnic) Co(II) complexes, namely, [Co(2-MeSnic)2L2(H2O)2].nH2O (L is N,N-diethylnicotinamide-Et2nia, ethylnicotinate-Etnic, nicotinamide-nia, isonicotinamide-isonia, N-methylnicotinamide-N-Menia, furo[3,2-c]pyridine-fpy, 2,3-dimethylfuro[3,2-c]pyridine-Me2fpy or benzo[4,5]furo[3,2-c]pyridine-Bfp; n is 0, 1 or 2) as well as [Co(2-MeSnic)2L2] (L is ronicol-ron or 2-methylfuro[3,2-c]pyridine-Mefpy), are reported. The characterizations werebased on physico-chemical and spectroscopic methods. The crystal structure of one of the complexes has been determined. In the molecular complex [Co(2-MeSnic)2(Me2fpy)2(H2O)2], the Co(II) central atom, located at a symmetry centre, is octahedrally coordinated by an oxygen atom of the unidentate 2-MeSnic carboxyl group, the nitrogen atom of the pyridine ring of Me2fpy, a water molecule and the corresponding centrosymmetrically located atoms. Also, biological activity of the complexes agai

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2008

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Transition Metal Chemistry

ISSN

0340-4285

e-ISSN

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Svazek periodika

33

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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