X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]- or [RuCl4(NO)(H2O)]- complex anions
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213203" target="_blank" >RIV/61989592:15310/10:10213203 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]- or [RuCl4(NO)(H2O)]- complex anions
Popis výsledku v původním jazyce
Three simple ruthenium nitrosyl complexes of the compositions [Et4N][RuCl4(NO)(DMSO](-) (1), [Bu4N][RuCl4(NO)(DMSO)](-) (2), and [Ph(4)P][RuCl4(NO)(H2O].DMSO (3); where DMSO = dimethyl sulfoxide, Et = ethyl, Bu = butyl and Ph = phenyl, have been synthesized in the single crystal form and their molecular and crystal structures have been determined. The Ru(II) centre is six-coordinated by four chlorido ligands in the equatorial plane and by the N (from NO+) and O (from DMSO in 1 and 2, H2O in 3) atoms inthe axial positions forming an RuCI4NO donor set. The complexes have been also characterized by infrared and electronic spectroscopies, conductivity measurements, and thermogravimetric (TG) and differential thermal (DTA) analyses. The spectroscopic investigation is consistent with the (Ru(NO))(6) formulation with NO+ coordinated to the diamagnetic Ru(II) centre. The geometries of the complex anions as well as spectroscopic properties were calculated at the B3LYP/LANL2DZ/cc-pVTZ level of
Název v anglickém jazyce
X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]- or [RuCl4(NO)(H2O)]- complex anions
Popis výsledku anglicky
Three simple ruthenium nitrosyl complexes of the compositions [Et4N][RuCl4(NO)(DMSO](-) (1), [Bu4N][RuCl4(NO)(DMSO)](-) (2), and [Ph(4)P][RuCl4(NO)(H2O].DMSO (3); where DMSO = dimethyl sulfoxide, Et = ethyl, Bu = butyl and Ph = phenyl, have been synthesized in the single crystal form and their molecular and crystal structures have been determined. The Ru(II) centre is six-coordinated by four chlorido ligands in the equatorial plane and by the N (from NO+) and O (from DMSO in 1 and 2, H2O in 3) atoms inthe axial positions forming an RuCI4NO donor set. The complexes have been also characterized by infrared and electronic spectroscopies, conductivity measurements, and thermogravimetric (TG) and differential thermal (DTA) analyses. The spectroscopic investigation is consistent with the (Ru(NO))(6) formulation with NO+ coordinated to the diamagnetic Ru(II) centre. The geometries of the complex anions as well as spectroscopic properties were calculated at the B3LYP/LANL2DZ/cc-pVTZ level of
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CA - Anorganická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
<a href="/cs/project/GP203%2F08%2FP436" target="_blank" >GP203/08/P436: Komplexy Ru a Rh s potenciální biologickou aktivitou</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2010
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Molecular Structure
ISSN
0022-2860
e-ISSN
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Svazek periodika
977
Číslo periodika v rámci svazku
1-3
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
7
Strana od-do
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Kód UT WoS článku
000280498600028
EID výsledku v databázi Scopus
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