[(eta(6)-p-cymene)Ru(H2O)(3)](2+) binding capability of aminohydroxamates - A solution and solid state study

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F16%3A00461986" target="_blank" >RIV/68081707:_____/16:00461986 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989592:15310/16:33161168

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.jinorgbio.2016.02.032" target="_blank" >http://dx.doi.org/10.1016/j.jinorgbio.2016.02.032</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jinorgbio.2016.02.032" target="_blank" >10.1016/j.jinorgbio.2016.02.032</a>

Jazyk výsledku

angličtina

Název v původním jazyce

[(eta(6)-p-cymene)Ru(H2O)(3)](2+) binding capability of aminohydroxamates - A solution and solid state study

Popis výsledku v původním jazyce

Complex forming capabilities of [(eta(6)-p-cymene)Ru(H2O)(3)](2+) with aminohydroxamates (2-amino-N-hydroxyacetamide (alpha-alahaH), 3-amino-N-hydroxypropanamide (beta-alahaH) and 4-amino-N-hydroxybutanamide (gamma-abhaH)) having the primary amino group in different chelatable position to the hydroxamic function were studied by pH-potentiometry, NMR and MS methods. Formation of stable [O,O] and mixed [O,O][N,N] chelated mono- and dinuclear species is detected in partially slow with alpha-alahaH and beta-alahaH or in fast processes with gamma-abhaH and the formation constants of the complexes present in aqueous solution are reported. Synthesis, spectral (NMR, IR) and ESI mass spectrometric characterization of novel dinuclear alpha-alaninehydroximato complexes containing the half-sandwich type Ru(II) core is described. The crystal and molecular structure of [{(eta(6)-p-cymene)Ru)(2)(mu(2)-alpha-alahaH(-1))(H2O)Br]Br center dot H2O (1) and [(eta(6)-p-cymene)Ru)(2)(mu(2)-alpha-alahaH(-1))(H2O)Cl]BF4 center dot H2O (2) was determined by single crystal X-ray diffraction method.

Název v anglickém jazyce

[(eta(6)-p-cymene)Ru(H2O)(3)](2+) binding capability of aminohydroxamates - A solution and solid state study

Popis výsledku anglicky

Complex forming capabilities of [(eta(6)-p-cymene)Ru(H2O)(3)](2+) with aminohydroxamates (2-amino-N-hydroxyacetamide (alpha-alahaH), 3-amino-N-hydroxypropanamide (beta-alahaH) and 4-amino-N-hydroxybutanamide (gamma-abhaH)) having the primary amino group in different chelatable position to the hydroxamic function were studied by pH-potentiometry, NMR and MS methods. Formation of stable [O,O] and mixed [O,O][N,N] chelated mono- and dinuclear species is detected in partially slow with alpha-alahaH and beta-alahaH or in fast processes with gamma-abhaH and the formation constants of the complexes present in aqueous solution are reported. Synthesis, spectral (NMR, IR) and ESI mass spectrometric characterization of novel dinuclear alpha-alaninehydroximato complexes containing the half-sandwich type Ru(II) core is described. The crystal and molecular structure of [{(eta(6)-p-cymene)Ru)(2)(mu(2)-alpha-alahaH(-1))(H2O)Br]Br center dot H2O (1) and [(eta(6)-p-cymene)Ru)(2)(mu(2)-alpha-alahaH(-1))(H2O)Cl]BF4 center dot H2O (2) was determined by single crystal X-ray diffraction method.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BO - Biofyzika

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Inorganic Biochemistry

ISSN

0162-0134

e-ISSN

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Svazek periodika

160

Číslo periodika v rámci svazku

JUL2016

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

236-245

Kód UT WoS článku

000378965200027

EID výsledku v databázi Scopus

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