Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33146056" target="_blank" >RIV/61989592:15310/13:33146056 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molstruc.2013.06.021" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2013.06.021</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2013.06.021" target="_blank" >10.1016/j.molstruc.2013.06.021</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3

Popis výsledku v původním jazyce

A mixed-ligand nickel(II) dithiocarbamate complex of the composition [Ni(bpdtc)(PPh3)2]ClO4PPh3 was synthesized, characterized (elemental analysis, UV-Vis, IR and NMR spectroscopy and molar conductivity measurements) and its X-ray structure was determined. The three ligands are arranged in a distorted square-planar geometry (an S2P2 donor set), with the bond lengths and angles within the vicinity of the central atom as follows: Ni-P = 2.2150(6) and 2.2529(6) ?, Ni-S = 2.2267(6) and 2.2129(6) ?, P-Ni-P =105.11(2), S-Ni-S = 78.26(2). The P-Ni-P angle of the studied complex falls outside the interval of 98.37-102.92 determined for thirteen formerly reported structural analogues involving the [Ni(ndtc)(PPh3)2]+ moiety with a combination of dithiocarbamate(ndtc) and triphenylphosphine (PPh3) ligands. In the crystal, the complex cations, perchlorate anions and PPh3 molecules of crystallization are linked through intramolecular C-H...O and C-H...pi and intermolecular C-H...O, C-H...C and C-

Název v anglickém jazyce

Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3

Popis výsledku anglicky

A mixed-ligand nickel(II) dithiocarbamate complex of the composition [Ni(bpdtc)(PPh3)2]ClO4PPh3 was synthesized, characterized (elemental analysis, UV-Vis, IR and NMR spectroscopy and molar conductivity measurements) and its X-ray structure was determined. The three ligands are arranged in a distorted square-planar geometry (an S2P2 donor set), with the bond lengths and angles within the vicinity of the central atom as follows: Ni-P = 2.2150(6) and 2.2529(6) ?, Ni-S = 2.2267(6) and 2.2129(6) ?, P-Ni-P =105.11(2), S-Ni-S = 78.26(2). The P-Ni-P angle of the studied complex falls outside the interval of 98.37-102.92 determined for thirteen formerly reported structural analogues involving the [Ni(ndtc)(PPh3)2]+ moiety with a combination of dithiocarbamate(ndtc) and triphenylphosphine (PPh3) ligands. In the crystal, the complex cations, perchlorate anions and PPh3 molecules of crystallization are linked through intramolecular C-H...O and C-H...pi and intermolecular C-H...O, C-H...C and C-

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

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Svazek periodika

1049

Číslo periodika v rámci svazku

OCT

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

5

Strana od-do

22-26

Kód UT WoS článku

000324784700004

EID výsledku v databázi Scopus

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