Colloidal maghemite nanoparticles with oxyhydroxide-like interface and chiroptical properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73602518" target="_blank" >RIV/61989592:15310/20:73602518 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0169433220323242" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0169433220323242</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.apsusc.2020.147567" target="_blank" >10.1016/j.apsusc.2020.147567</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Colloidal maghemite nanoparticles with oxyhydroxide-like interface and chiroptical properties

Popis výsledku v původním jazyce

Magnetic nanoparticles, mainly constituted of magnetite and maghemite, are widely used for environmental, biomedical and biotechnological applications. Herein, the synthesis and properties of maghemite nanoparticles characterized by chiroptical activity, representing an unprecedented feature for iron oxide nanoparticles, is described in detail. Among nanosized iron oxides, these maghemite nanoparticles stand out for the excellent colloidal stability in water and the witnessed ability to specifically bind selected molecules. The surface properties of nanoparticles were probed with As-III and As-V oxyacids, studied by x-ray photoelectron spectroscopy and correlated to circular dichroism. The dichroic signal of nanoparticles was differently influenced by the coordination of ligands. Crystalline vacancies on the nanomaterial surface were identified as the chiral centers responsible of the dichroic behavior and the selectivity toward ligands. The latter was correlated with the ability of restructuring the nanomaterial at the crystal truncation. Furthermore, surface binding sites emerged for bearing labile coordination water in analogy with iron oxyhydroxides. The present report, besides enriching the colloidal chemistry of iron oxide based nanomaterials, can stimulate further research on inorganic systems expressing intrinsic chiral properties.

Název v anglickém jazyce

Colloidal maghemite nanoparticles with oxyhydroxide-like interface and chiroptical properties

Popis výsledku anglicky

Magnetic nanoparticles, mainly constituted of magnetite and maghemite, are widely used for environmental, biomedical and biotechnological applications. Herein, the synthesis and properties of maghemite nanoparticles characterized by chiroptical activity, representing an unprecedented feature for iron oxide nanoparticles, is described in detail. Among nanosized iron oxides, these maghemite nanoparticles stand out for the excellent colloidal stability in water and the witnessed ability to specifically bind selected molecules. The surface properties of nanoparticles were probed with As-III and As-V oxyacids, studied by x-ray photoelectron spectroscopy and correlated to circular dichroism. The dichroic signal of nanoparticles was differently influenced by the coordination of ligands. Crystalline vacancies on the nanomaterial surface were identified as the chiral centers responsible of the dichroic behavior and the selectivity toward ligands. The latter was correlated with the ability of restructuring the nanomaterial at the crystal truncation. Furthermore, surface binding sites emerged for bearing labile coordination water in analogy with iron oxyhydroxides. The present report, besides enriching the colloidal chemistry of iron oxide based nanomaterials, can stimulate further research on inorganic systems expressing intrinsic chiral properties.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/EF17_048%2F0007323" target="_blank" >EF17_048/0007323: Rozvoj předaplikačního výzkumu v oblasti nano- a biotechnologií</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

APPLIED SURFACE SCIENCE

ISSN

0169-4332

e-ISSN

—

Svazek periodika

534

Číslo periodika v rámci svazku

DEC

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

"147567-1"-"147567-11"

Kód UT WoS článku

000582367700015

EID výsledku v databázi Scopus

2-s2.0-85089807593