The occurrence of Cannizzaro reaction over Mg-Al hydrotalcites

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F16%3AN0000006" target="_blank" >RIV/62243136:_____/16:N0000006 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.sciencedirect.com/science/article/pii/S0926860X16304148" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0926860X16304148</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.apcata.2016.08.007" target="_blank" >10.1016/j.apcata.2016.08.007</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The occurrence of Cannizzaro reaction over Mg-Al hydrotalcites

Popis výsledku v původním jazyce

Mg-Al mixed oxides and reconstructed hydrotalcites prepared from mixed oxides by rehydration attract much attention as solid basic catalysts for organic reactions, such as aldol condensation. Therefore, the understanding of parameters that govern their catalytic performance is of great importance. Cannizzaro reaction in the presence of mixed oxide and reconstructed HTC as basic catalysts was used as a model reaction to characterize both catalytic systems and to understand their behavior in aldol condensation. The performance of the samples was investigated in the conversion of aqueous furfural mixture using stirred batch reactor operating at T = 50 °C. The properties of both initial samples and catalysts after reaction were studied by different physico-chemical methods, such as XRD, DRIFT and TGA. It was shown that both mixed oxide and reconstructed HTC possessed poor activity in the conversion of dried furfural proving the importance of water presence for the reaction to take place. Addition of water to the reaction mixture resulted in growth of the yield of both furfuryl alcohol and furoyl furoate as reaction products. Furoic acid was not identified by GC analysis, but the interaction of the acid with the basic sites of catalysts was confirmed by DRIFT and TGA analyses indicating that at optimum reaction conditions, most of the basic sites were involved in the formation of furoate species. The formation of the surface furoate species influenced the behavior of the basic catalysts in aldol condensation of furfural and acetone. It allows concluding that the occurrence of Cannizzaro reaction should be taken into account when considering the behavior of basic catalysts in organic reactions with furfural as a reactant.

Název v anglickém jazyce

The occurrence of Cannizzaro reaction over Mg-Al hydrotalcites

Popis výsledku anglicky

Mg-Al mixed oxides and reconstructed hydrotalcites prepared from mixed oxides by rehydration attract much attention as solid basic catalysts for organic reactions, such as aldol condensation. Therefore, the understanding of parameters that govern their catalytic performance is of great importance. Cannizzaro reaction in the presence of mixed oxide and reconstructed HTC as basic catalysts was used as a model reaction to characterize both catalytic systems and to understand their behavior in aldol condensation. The performance of the samples was investigated in the conversion of aqueous furfural mixture using stirred batch reactor operating at T = 50 °C. The properties of both initial samples and catalysts after reaction were studied by different physico-chemical methods, such as XRD, DRIFT and TGA. It was shown that both mixed oxide and reconstructed HTC possessed poor activity in the conversion of dried furfural proving the importance of water presence for the reaction to take place. Addition of water to the reaction mixture resulted in growth of the yield of both furfuryl alcohol and furoyl furoate as reaction products. Furoic acid was not identified by GC analysis, but the interaction of the acid with the basic sites of catalysts was confirmed by DRIFT and TGA analyses indicating that at optimum reaction conditions, most of the basic sites were involved in the formation of furoate species. The formation of the surface furoate species influenced the behavior of the basic catalysts in aldol condensation of furfural and acetone. It allows concluding that the occurrence of Cannizzaro reaction should be taken into account when considering the behavior of basic catalysts in organic reactions with furfural as a reactant.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Vývoj nových nanoporézních adsorbentů a katalyzátorů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Applied Catalysis A: General

ISSN

0926860x

e-ISSN

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Svazek periodika

525

Číslo periodika v rámci svazku

525

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

215–225

Kód UT WoS článku

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EID výsledku v databázi Scopus

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