Speeds of Sound, Isentropic Compressibilities and Refractive Indices for Some Binary Mixtures of Nitromethane with Chloroalkane at Temperatures from 298.15 to 318.15?K. Comparison with Theories

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F15%3A00440899" target="_blank" >RIV/67985858:_____/15:00440899 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.fluid.2014.10.004" target="_blank" >http://dx.doi.org/10.1016/j.fluid.2014.10.004</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.fluid.2014.10.004" target="_blank" >10.1016/j.fluid.2014.10.004</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Speeds of Sound, Isentropic Compressibilities and Refractive Indices for Some Binary Mixtures of Nitromethane with Chloroalkane at Temperatures from 298.15 to 318.15?K. Comparison with Theories

Popis výsledku v původním jazyce

The experimental data of speed of sound and refractive index for eight binary liquid mixtures of nitromethane with: 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, 1,2- dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane and 1-chloropentane, have been measured at temperatures in the range of 298.15-318.15 K and atmospheric pressure. From the experimental data of densities and speeds of sound, the isentropic compressibilities and the excess isentropic compressibilities were calculated and from the experimental data of refractive indices, the deviation in refractive indices and the molar refractions have been computed. These excess properties of the binary mixtures were correlated by the Redlich-Kister type polynomials using a robust regression along a gnostic influence function. Speeds of sound and isentropic compressibilities have been compared with calculated values from Jacobson free length theory (FLT), Nomoto?s relation (NR), Zhang Junjie?s r

Název v anglickém jazyce

Speeds of Sound, Isentropic Compressibilities and Refractive Indices for Some Binary Mixtures of Nitromethane with Chloroalkane at Temperatures from 298.15 to 318.15?K. Comparison with Theories

Popis výsledku anglicky

The experimental data of speed of sound and refractive index for eight binary liquid mixtures of nitromethane with: 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, 1,2- dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane and 1-chloropentane, have been measured at temperatures in the range of 298.15-318.15 K and atmospheric pressure. From the experimental data of densities and speeds of sound, the isentropic compressibilities and the excess isentropic compressibilities were calculated and from the experimental data of refractive indices, the deviation in refractive indices and the molar refractions have been computed. These excess properties of the binary mixtures were correlated by the Redlich-Kister type polynomials using a robust regression along a gnostic influence function. Speeds of sound and isentropic compressibilities have been compared with calculated values from Jacobson free length theory (FLT), Nomoto?s relation (NR), Zhang Junjie?s r

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Fluid Phase Equilibria

ISSN

0378-3812

e-ISSN

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Svazek periodika

385

Číslo periodika v rámci svazku

JAN 15

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

5

Strana od-do

105-109

Kód UT WoS článku

000347578400012

EID výsledku v databázi Scopus

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