Volumetric, Acoustic and Optical Properties for Binary Mixtures of Nitroethane with Chloroalkane at Temperatures between 298.15 K and 318.15 K. Comparison with Theories.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F16%3A00463362" target="_blank" >RIV/67985858:_____/16:00463362 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molliq.2016.08.076" target="_blank" >http://dx.doi.org/10.1016/j.molliq.2016.08.076</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molliq.2016.08.076" target="_blank" >10.1016/j.molliq.2016.08.076</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Volumetric, Acoustic and Optical Properties for Binary Mixtures of Nitroethane with Chloroalkane at Temperatures between 298.15 K and 318.15 K. Comparison with Theories.

Popis výsledku v původním jazyce

In a continuation from a previous work, experimental densities, speeds of sound, and refractive indices data, for eight binary liquid mixtures of nitroethane with 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane and 1-chloropentane were measured in the temperature range of (298.15–318.15) K and at atmospheric pressure. From the measured data the derived properties, such as the excess molar volumes, the isentropic compressibility, the deviations in isentropic compressibility, the deviations in refractive indices, the molar refractions and the deviations in molar refractions data have been calculated. The excess properties of the binary mixtures were correlated by the Redlich–Kister type polynomials using a robust regression along the gnostic influence function. Speed of sound and isentropic compressibility data have been compared with calculated values from Jacobson free length theory (FLT), Nomoto's relation (NR), Zhang Junjie's relation (JR), Van Deal's ideal mixing relation (IMR), Impedance dependence relation (IDR) and Schaaff's collision factor theory (CFT). The ability of different theoretical (n,ρ) mixing rules (Lorentz–Lorenz, Gladstone–Dale, Arago–Biot, Edwards and Eykman) to predict the refractive indices was evaluated. The experimental and calculated results are discussed in terms of molecular interactions and structural effects between components of mixtures.

Název v anglickém jazyce

Volumetric, Acoustic and Optical Properties for Binary Mixtures of Nitroethane with Chloroalkane at Temperatures between 298.15 K and 318.15 K. Comparison with Theories.

Popis výsledku anglicky

In a continuation from a previous work, experimental densities, speeds of sound, and refractive indices data, for eight binary liquid mixtures of nitroethane with 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane and 1-chloropentane were measured in the temperature range of (298.15–318.15) K and at atmospheric pressure. From the measured data the derived properties, such as the excess molar volumes, the isentropic compressibility, the deviations in isentropic compressibility, the deviations in refractive indices, the molar refractions and the deviations in molar refractions data have been calculated. The excess properties of the binary mixtures were correlated by the Redlich–Kister type polynomials using a robust regression along the gnostic influence function. Speed of sound and isentropic compressibility data have been compared with calculated values from Jacobson free length theory (FLT), Nomoto's relation (NR), Zhang Junjie's relation (JR), Van Deal's ideal mixing relation (IMR), Impedance dependence relation (IDR) and Schaaff's collision factor theory (CFT). The ability of different theoretical (n,ρ) mixing rules (Lorentz–Lorenz, Gladstone–Dale, Arago–Biot, Edwards and Eykman) to predict the refractive indices was evaluated. The experimental and calculated results are discussed in terms of molecular interactions and structural effects between components of mixtures.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

—

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Liquids

ISSN

0167-7322

e-ISSN

—

Svazek periodika

223

Číslo periodika v rámci svazku

NOV 2016

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

15

Strana od-do

790-804

Kód UT WoS článku

000386986300095

EID výsledku v databázi Scopus

2-s2.0-84986295362