Influence of iridium (Ir) doping on the structural, electrical, and dielectric properties of LuFeO3 perovskite compound

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F21%3A00543763" target="_blank" >RIV/68081723:_____/21:00543763 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216305:26620/21:PU141350

Výsledek na webu

<a href="https://reader.elsevier.com/reader/sd/pii/S0925838821016911?token=A48DB5CB7ED696AE6B1490A87B29465551BD63F16BD5AB2BB1F261A98C1C7EE9D2FE87F017938A9CA0F1D42CC8AFE55F&originRegion=eu-west-1&originCreation=20210713132815" target="_blank" >https://reader.elsevier.com/reader/sd/pii/S0925838821016911?token=A48DB5CB7ED696AE6B1490A87B29465551BD63F16BD5AB2BB1F261A98C1C7EE9D2FE87F017938A9CA0F1D42CC8AFE55F&originRegion=eu-west-1&originCreation=20210713132815</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jallcom.2021.160282" target="_blank" >10.1016/j.jallcom.2021.160282</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Influence of iridium (Ir) doping on the structural, electrical, and dielectric properties of LuFeO3 perovskite compound

Popis výsledku v původním jazyce

Rare-earth ferrites have been intensively investigated owing to their magnetic, electrical, and optical features in the literature. The present quest goals to examine the electrical properties of LuFeO3 (LFO) and LuFe1-xIrxO3 (LFIO) ceramics with different mol%, x = 0.05 and 0.10. X-ray diffractometer (XRD) method was utilized to identify the crystal nature of the obtained powders. The scanning electron microscope (SEM) was exploited to examine the surface topography of the fabricated pellets. X-ray photoelectron spectroscopy (XPS) was employed to find out the valence states of lutetium (Lu) (data is not presented here), iron (Fe), and iridium (Ir). Electrical modulus, dielectric constant, and conductivity of LFO and LFIO ceramics were detailed by dielectric/impedance spectroscopy measurements, which were performed at between 100 degrees C (173 K) up to 100 degrees C (373 K) with 20 degrees C temperature step. It was exhibited that the undoped LFO has a higher dielectric constant and conductivity than the Ir doped samples. Such a decrement in both dielectric constants and conductivity was related to i) reduction in the ratio of Fe2+ ions and ii) defects and/or distortion in the LFO structure due to Ir substitution. (C) 2021 Elsevier B.V. All rights reserved.

Název v anglickém jazyce

Influence of iridium (Ir) doping on the structural, electrical, and dielectric properties of LuFeO3 perovskite compound

Popis výsledku anglicky

Rare-earth ferrites have been intensively investigated owing to their magnetic, electrical, and optical features in the literature. The present quest goals to examine the electrical properties of LuFeO3 (LFO) and LuFe1-xIrxO3 (LFIO) ceramics with different mol%, x = 0.05 and 0.10. X-ray diffractometer (XRD) method was utilized to identify the crystal nature of the obtained powders. The scanning electron microscope (SEM) was exploited to examine the surface topography of the fabricated pellets. X-ray photoelectron spectroscopy (XPS) was employed to find out the valence states of lutetium (Lu) (data is not presented here), iron (Fe), and iridium (Ir). Electrical modulus, dielectric constant, and conductivity of LFO and LFIO ceramics were detailed by dielectric/impedance spectroscopy measurements, which were performed at between 100 degrees C (173 K) up to 100 degrees C (373 K) with 20 degrees C temperature step. It was exhibited that the undoped LFO has a higher dielectric constant and conductivity than the Ir doped samples. Such a decrement in both dielectric constants and conductivity was related to i) reduction in the ratio of Fe2+ ions and ii) defects and/or distortion in the LFO structure due to Ir substitution. (C) 2021 Elsevier B.V. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/LM2018110" target="_blank" >LM2018110: Výzkumná infrastruktura CzechNanoLab</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Alloys and Compounds

ISSN

0925-8388

e-ISSN

1873-4669

Svazek periodika

877

Číslo periodika v rámci svazku

OCT

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

14

Strana od-do

160282

Kód UT WoS článku

000660433800005

EID výsledku v databázi Scopus

2-s2.0-85105712965