Synthesis of new cobalt(III) Schiff base complex: a new precursor for preparation Co3O4 nanoparticles via solid-state thermal decomposition

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00435001" target="_blank" >RIV/68378271:_____/14:00435001 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molstruc.2014.04.043" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2014.04.043</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2014.04.043" target="_blank" >10.1016/j.molstruc.2014.04.043</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis of new cobalt(III) Schiff base complex: a new precursor for preparation Co3O4 nanoparticles via solid-state thermal decomposition

Popis výsledku v původním jazyce

A new mononuclear octahedral cobalt(III) Schiff base complex has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy and used as precursor for preparation of Co3O4 nanoparticles. The crystal structure of this compound has been determined by single-crystal X-ray diffraction. The coordination sphere about cobalt(III) ion consists of three phenolato oxygens and three imino nitrogen atoms from three Schiff base ligands, thus forming a distorted octahedral geometry. Each Schiff base ligand acts as a chelate using phenolato oxygen and imino nitrogen. Subsequently, pure phase Co3O4 nanoparticles, with an average size in the range 10?20 nm, were obtained by solid-state thermal decomposition of the synthesized complex at 450 degC under air atmosphere for 3 h.

Název v anglickém jazyce

Synthesis of new cobalt(III) Schiff base complex: a new precursor for preparation Co3O4 nanoparticles via solid-state thermal decomposition

Popis výsledku anglicky

A new mononuclear octahedral cobalt(III) Schiff base complex has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy and used as precursor for preparation of Co3O4 nanoparticles. The crystal structure of this compound has been determined by single-crystal X-ray diffraction. The coordination sphere about cobalt(III) ion consists of three phenolato oxygens and three imino nitrogen atoms from three Schiff base ligands, thus forming a distorted octahedral geometry. Each Schiff base ligand acts as a chelate using phenolato oxygen and imino nitrogen. Subsequently, pure phase Co3O4 nanoparticles, with an average size in the range 10?20 nm, were obtained by solid-state thermal decomposition of the synthesized complex at 450 degC under air atmosphere for 3 h.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BM - Fyzika pevných látek a magnetismus

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

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Svazek periodika

1071

Číslo periodika v rámci svazku

Aug

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

5

Strana od-do

6-10

Kód UT WoS článku

000338821800002

EID výsledku v databázi Scopus

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