Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00436124" target="_blank" >RIV/68378271:_____/15:00436124 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.saa.2014.08.070" target="_blank" >http://dx.doi.org/10.1016/j.saa.2014.08.070</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.saa.2014.08.070" target="_blank" >10.1016/j.saa.2014.08.070</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure

Popis výsledku v původním jazyce

Two new cadmium(II) complexes with the formula CdL2(NCS)2 and CdL2(N3)2 (L = 2,2-dimethyl-N,N0 -bis-(3-phenyl-allylidene)-propane-1,3-diamine) have been synthesized and characterized by elemental analysis, molar conductivity measurements, FT/IR, UV-Visible, 1H and 13C NMR spectra and X-ray studies. Two Schiff base ligands are bonded to cadmium(II) ion as N2-donor chelate. Coordination geometry around the cadmium is a octahedron. The C-H? and C-HS nteractions give rise a supramolecular structure. The cadmium complexes were screened in vitro for their antibacterial and antifungal activities. Moreover, the compounds were subjected for DNA-cleavage potential by gel electrophoresis method. Finally thermo-gravimetric analysis of the complexes was applied forthermal behavior studies and basic thermo-kinetics activation parameters were evaluated.

Název v anglickém jazyce

Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure

Popis výsledku anglicky

Two new cadmium(II) complexes with the formula CdL2(NCS)2 and CdL2(N3)2 (L = 2,2-dimethyl-N,N0 -bis-(3-phenyl-allylidene)-propane-1,3-diamine) have been synthesized and characterized by elemental analysis, molar conductivity measurements, FT/IR, UV-Visible, 1H and 13C NMR spectra and X-ray studies. Two Schiff base ligands are bonded to cadmium(II) ion as N2-donor chelate. Coordination geometry around the cadmium is a octahedron. The C-H? and C-HS nteractions give rise a supramolecular structure. The cadmium complexes were screened in vitro for their antibacterial and antifungal activities. Moreover, the compounds were subjected for DNA-cleavage potential by gel electrophoresis method. Finally thermo-gravimetric analysis of the complexes was applied forthermal behavior studies and basic thermo-kinetics activation parameters were evaluated.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BM - Fyzika pevných látek a magnetismus

OECD FORD obor

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Projekt

<a href="/cs/project/GA14-03276S" target="_blank" >GA14-03276S: Nesférické efekty a jejich využití pro statisticky korektní analýzu krystalových struktur</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy

ISSN

1386-1425

e-ISSN

—

Svazek periodika

137

Číslo periodika v rámci svazku

FEB

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

8

Strana od-do

389-396

Kód UT WoS článku

000347269900054

EID výsledku v databázi Scopus

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