Hydrogen peroxide coordination to cobalt(II) facilitated by second-sphere hydrogen bonding

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00467737" target="_blank" >RIV/68378271:_____/16:00467737 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1002/anie.201606561" target="_blank" >https://doi.org/10.1002/anie.201606561</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/anie.201606561" target="_blank" >10.1002/anie.201606561</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Hydrogen peroxide coordination to cobalt(II) facilitated by second-sphere hydrogen bonding

Popis výsledku v původním jazyce

M(H2O2) adducts have been postulated as intermediates in biological and industrial processes however, only one observable M(H2O2) adduct has been reported, where M is redox-inactive zinc. Herein, direct solution-phase detection of an M(H2O2) adduct with a redox-active metal, cobalt(II), is described. This CoII(H2O2) compound is made observable by incorporating second-sphere hydrogen-bonding interactions between bound (H2O2) and the supporting ligand, a trianionic trisulfonamido ligand. Thermodynamics of (H2O2) binding and decay kinetics of the CoII(H2O2) species are described, as well as the reaction of this CoII(H2O2)species with Group 2 cations.n

Název v anglickém jazyce

Hydrogen peroxide coordination to cobalt(II) facilitated by second-sphere hydrogen bonding

Popis výsledku anglicky

M(H2O2) adducts have been postulated as intermediates in biological and industrial processes however, only one observable M(H2O2) adduct has been reported, where M is redox-inactive zinc. Herein, direct solution-phase detection of an M(H2O2) adduct with a redox-active metal, cobalt(II), is described. This CoII(H2O2) compound is made observable by incorporating second-sphere hydrogen-bonding interactions between bound (H2O2) and the supporting ligand, a trianionic trisulfonamido ligand. Thermodynamics of (H2O2) binding and decay kinetics of the CoII(H2O2) species are described, as well as the reaction of this CoII(H2O2)species with Group 2 cations.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Angewandte Chemie - International Edition

ISSN

1433-7851

e-ISSN

—

Svazek periodika

55

Číslo periodika v rámci svazku

39

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

5

Strana od-do

11902-11906

Kód UT WoS článku

000384713100034

EID výsledku v databázi Scopus

2-s2.0-84994406593