Surface morphology-assisted electrochemical conversion of carbon dioxide to formic acid via nanocrystalline boron-doped diamond electrodes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00574390" target="_blank" >RIV/68378271:_____/23:00574390 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.cej.2023.145463" target="_blank" >https://doi.org/10.1016/j.cej.2023.145463</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.cej.2023.145463" target="_blank" >10.1016/j.cej.2023.145463</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Surface morphology-assisted electrochemical conversion of carbon dioxide to formic acid via nanocrystalline boron-doped diamond electrodes

Popis výsledku v původním jazyce

Due to its unmatched corrosion stability and overall versatility, boron-doped diamond (BDD) has superb potential as an electrode material for the production of valuable chemicals via electrochemical reduction of carbon dioxide (CO2). To advance its practical application, it is necessary to explore ways to achieve cost-effective fabrication of BDD electrodes, which can enable significant selectivity for product formation during CO2 electroreduction. Here, BDD electrodes of nanocrystalline form were fabricated employing two distinct chemical vapor deposition (CVD) techniques, which allow for substantial upscaling of electrode dimensions to match industrial/wafer-size standards. Thin (<400 nm) nanocrystalline BDD layers were fabricated at various synthesis temperatures to investigate its effect on the electrical, structural, and electrochemical characteristics.

Název v anglickém jazyce

Surface morphology-assisted electrochemical conversion of carbon dioxide to formic acid via nanocrystalline boron-doped diamond electrodes

Popis výsledku anglicky

Due to its unmatched corrosion stability and overall versatility, boron-doped diamond (BDD) has superb potential as an electrode material for the production of valuable chemicals via electrochemical reduction of carbon dioxide (CO2). To advance its practical application, it is necessary to explore ways to achieve cost-effective fabrication of BDD electrodes, which can enable significant selectivity for product formation during CO2 electroreduction. Here, BDD electrodes of nanocrystalline form were fabricated employing two distinct chemical vapor deposition (CVD) techniques, which allow for substantial upscaling of electrode dimensions to match industrial/wafer-size standards. Thin (<400 nm) nanocrystalline BDD layers were fabricated at various synthesis temperatures to investigate its effect on the electrical, structural, and electrochemical characteristics.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

<a href="/cs/project/GJ19-09784Y" target="_blank" >GJ19-09784Y: Nanokrystalické diamantové elektrody pro fotoelektrochemické aplikace: redukce CO2 a degradace organických kontaminantů ve vodě</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemical Engineering Journal

ISSN

1385-8947

e-ISSN

1873-3212

Svazek periodika

473

Číslo periodika v rámci svazku

Oct

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

13

Strana od-do

145463

Kód UT WoS článku

001064027400001

EID výsledku v databázi Scopus

2-s2.0-85168493889