Reactivity of precursors for geopolymerization studied by isothermal calorimetry

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21110%2F24%3A00377388" target="_blank" >RIV/68407700:21110/24:00377388 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1007/s10973-024-13492-y" target="_blank" >https://doi.org/10.1007/s10973-024-13492-y</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10973-024-13492-y" target="_blank" >10.1007/s10973-024-13492-y</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Reactivity of precursors for geopolymerization studied by isothermal calorimetry

Popis výsledku v původním jazyce

The paper deals with analyzes of Isothermal Conduction Calorimetry response obtained during the alkaline activation of four types of precursors (metakaolin, slag and two kinds of waste ceramic powders) to geopolymers. The first two precursors are traditionally used, while the latter two are emerging materials and knowledge of their alkaline activation might have high importance in the recycling of Construction and Demolition Waste. The studied precursors differ each to other not only in the chemical composition, but also in the phase composition-the waste ceramic precursors are highly crystalline. It was found that the total reaction heat evolved in the geopolymerization is directly proportional to the amorphous matter content as well as to the compressive strength of the activated product. This finding can be used as fast evaluation tool in searching of new potential geopolymer precursors. The dissolution and polycondensation steps were observed in all experiments and their kinetics was described by Jander's equation. While the rate of dissolution step is not dependent on temperature, the polycondensation has been accelerated by the higher temperature. The level of the rate acceleration was described by apparent activation energy; these findings can be useful in tuning of geopolymers curing procedure.

Název v anglickém jazyce

Reactivity of precursors for geopolymerization studied by isothermal calorimetry

Popis výsledku anglicky

The paper deals with analyzes of Isothermal Conduction Calorimetry response obtained during the alkaline activation of four types of precursors (metakaolin, slag and two kinds of waste ceramic powders) to geopolymers. The first two precursors are traditionally used, while the latter two are emerging materials and knowledge of their alkaline activation might have high importance in the recycling of Construction and Demolition Waste. The studied precursors differ each to other not only in the chemical composition, but also in the phase composition-the waste ceramic precursors are highly crystalline. It was found that the total reaction heat evolved in the geopolymerization is directly proportional to the amorphous matter content as well as to the compressive strength of the activated product. This finding can be used as fast evaluation tool in searching of new potential geopolymer precursors. The dissolution and polycondensation steps were observed in all experiments and their kinetics was described by Jander's equation. While the rate of dissolution step is not dependent on temperature, the polycondensation has been accelerated by the higher temperature. The level of the rate acceleration was described by apparent activation energy; these findings can be useful in tuning of geopolymers curing procedure.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Projekt

<a href="/cs/project/GA23-04772S" target="_blank" >GA23-04772S: Fyzikální a chemické procesy v alkalicky aktivované keramice vystavené vysokým teplotám</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Thermal Analysis and Calorimetry

ISSN

1388-6150

e-ISSN

1588-2926

Svazek periodika

149

Číslo periodika v rámci svazku

19

Stát vydavatele periodika

HU - Maďarsko

Počet stran výsledku

13

Strana od-do

10619-10631

Kód UT WoS článku

001296518800002

EID výsledku v databázi Scopus

2-s2.0-85201815738