Influence of Ag alloying on the morphology, structure, mechanical properties, thermal stability and oxidation resistance of multilayered TiSiN/Ti(Ag)N films

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21230%2F20%3A00343443" target="_blank" >RIV/68407700:21230/20:00343443 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.matdes.2020.108703" target="_blank" >https://doi.org/10.1016/j.matdes.2020.108703</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.matdes.2020.108703" target="_blank" >10.1016/j.matdes.2020.108703</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Influence of Ag alloying on the morphology, structure, mechanical properties, thermal stability and oxidation resistance of multilayered TiSiN/Ti(Ag)N films

Popis výsledku v původním jazyce

Self-lubricant films combine the intrinsic properties of high oxidation resistance coatings with lubricious elements deposited as monolayer and/or multilayered configuration, offering an opportunity to design green coating materials. The present paper reports the influence of Ag additions (range 0-3.2 at.%), considered as low friction material, on the morphology, structure, mechanical properties, thermal stability and oxidation resistance of multilayered TiSiN/TiN(Ag) films deposited by sputtering. The surface morphology of the coatings progressively changed from a well-defined cauliflower structure to a tetrahedral and pyramid-like structure and the cross-section morphology became more compact with Ag incorporation. A decrease of coating's hardness and Young's modulus was observed with Ag additions, due to the incorporation of the soft silver on the structure. The coatings showed excellent thermal stability and revealed a good control to the Ag diffusion towards the surface in protective atmosphere. Ag additions did not affect the onset oxidation point of films. However, the oxidation resistance of the films was reduced with Ag inclusion, due to its additional transportation during the oxidation process, promoting additional paths for ions diffusion, giving rise to a less protective Ti-Si-O layer and contributing to the formation of big crystals of rutile on the top. (c) 2020 The Authors. Published by Elsevier Ltd.

Název v anglickém jazyce

Influence of Ag alloying on the morphology, structure, mechanical properties, thermal stability and oxidation resistance of multilayered TiSiN/Ti(Ag)N films

Popis výsledku anglicky

Self-lubricant films combine the intrinsic properties of high oxidation resistance coatings with lubricious elements deposited as monolayer and/or multilayered configuration, offering an opportunity to design green coating materials. The present paper reports the influence of Ag additions (range 0-3.2 at.%), considered as low friction material, on the morphology, structure, mechanical properties, thermal stability and oxidation resistance of multilayered TiSiN/TiN(Ag) films deposited by sputtering. The surface morphology of the coatings progressively changed from a well-defined cauliflower structure to a tetrahedral and pyramid-like structure and the cross-section morphology became more compact with Ag incorporation. A decrease of coating's hardness and Young's modulus was observed with Ag additions, due to the incorporation of the soft silver on the structure. The coatings showed excellent thermal stability and revealed a good control to the Ag diffusion towards the surface in protective atmosphere. Ag additions did not affect the onset oxidation point of films. However, the oxidation resistance of the films was reduced with Ag inclusion, due to its additional transportation during the oxidation process, promoting additional paths for ions diffusion, giving rise to a less protective Ti-Si-O layer and contributing to the formation of big crystals of rutile on the top. (c) 2020 The Authors. Published by Elsevier Ltd.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20506 - Coating and films

Projekt

<a href="/cs/project/EF18_070%2F0010457" target="_blank" >EF18_070/0010457: Mezinárodní mobility výzkumných pracovníků MSCA-IF II na ČVUT v Praze</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials & Design

ISSN

0264-1275

e-ISSN

1873-4197

Svazek periodika

192

Číslo periodika v rámci svazku

July

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

9

Strana od-do

—

Kód UT WoS článku

000568683200006

EID výsledku v databázi Scopus

2-s2.0-85082927534