Effect of N, C, and B interstitials on the structural and magnetic properties of alloys with Cu3Au structure

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21230%2F20%3A00346199" target="_blank" >RIV/68407700:21230/20:00346199 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1103/PhysRevResearch.2.023134" target="_blank" >https://doi.org/10.1103/PhysRevResearch.2.023134</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1103/PhysRevResearch.2.023134" target="_blank" >10.1103/PhysRevResearch.2.023134</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Effect of N, C, and B interstitials on the structural and magnetic properties of alloys with Cu3Au structure

Popis výsledku v původním jazyce

High-throughput density functional calculations are used to investigate the effect of interstitial B, C, and N atoms on 21 alloys reported to crystallize in the cubic Cu3Au structure. It is shown that the interstitials can have a significant impact on the magnetocrystalline anisotropy energy (MAE), the thermodynamic stability, and the magnetic ground-state structure, making these alloys interesting for hard magnetic, magnetocaloric, and other applications. For 29 alloy-interstitial combinations the formation of stable alloys with interstitial concentrations above 5% is expected. In Ni3Mn interstitial N induces a tetragonal distortion with substantial uniaxial MAE for realistic N concentrations. Mn3XNx (X = Rh, Ir, Pt, and Sb) compounds are identified as alloys with strong magnetocrystalline anisotropy. For Mn3Ir we find a strong enhancement of the MAE upon N alloying in the most stable collinear ferrimagnetic state as well as in the noncollinear magnetic ground state. Mn3Ir and Mn3IrN also show interesting topological transport properties. The effects of N concentration and strain on the magnetic properties are discussed. Further, the huge impact of N on the MAE of Mn3Ir and a possible impact of interstitial N on amorphous Mn3Ir, a material that is indispensable in today's data storage devices, are discussed in relation to the electronic structure. For Mn3Sb, noncollinear, ferrimagnetic, and ferromagnetic states are very close in energy, making this material potentially interesting for magnetocaloric applications. For the investigated Mn alloys and competing phases, the determination of the magnetic ground state is essential for a reliable prediction of the phase stability.

Název v anglickém jazyce

Effect of N, C, and B interstitials on the structural and magnetic properties of alloys with Cu3Au structure

Popis výsledku anglicky

High-throughput density functional calculations are used to investigate the effect of interstitial B, C, and N atoms on 21 alloys reported to crystallize in the cubic Cu3Au structure. It is shown that the interstitials can have a significant impact on the magnetocrystalline anisotropy energy (MAE), the thermodynamic stability, and the magnetic ground-state structure, making these alloys interesting for hard magnetic, magnetocaloric, and other applications. For 29 alloy-interstitial combinations the formation of stable alloys with interstitial concentrations above 5% is expected. In Ni3Mn interstitial N induces a tetragonal distortion with substantial uniaxial MAE for realistic N concentrations. Mn3XNx (X = Rh, Ir, Pt, and Sb) compounds are identified as alloys with strong magnetocrystalline anisotropy. For Mn3Ir we find a strong enhancement of the MAE upon N alloying in the most stable collinear ferrimagnetic state as well as in the noncollinear magnetic ground state. Mn3Ir and Mn3IrN also show interesting topological transport properties. The effects of N concentration and strain on the magnetic properties are discussed. Further, the huge impact of N on the MAE of Mn3Ir and a possible impact of interstitial N on amorphous Mn3Ir, a material that is indispensable in today's data storage devices, are discussed in relation to the electronic structure. For Mn3Sb, noncollinear, ferrimagnetic, and ferromagnetic states are very close in energy, making this material potentially interesting for magnetocaloric applications. For the investigated Mn alloys and competing phases, the determination of the magnetic ground state is essential for a reliable prediction of the phase stability.

Druh

J_ost - Ostatní články v recenzovaných periodicích

CEP obor

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OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/EF18_070%2F0010457" target="_blank" >EF18_070/0010457: Mezinárodní mobility výzkumných pracovníků MSCA-IF II na ČVUT v Praze</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Physical Review Research

ISSN

2643-1564

e-ISSN

2643-1564

Svazek periodika

2

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

12

Strana od-do

—

Kód UT WoS článku

000603561200007

EID výsledku v databázi Scopus

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