Cucurbit[n]urils-related Multitopic Supramolecular Components: Design, Properties, and Perspectives

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F18%3A63520474" target="_blank" >RIV/70883521:28110/18:63520474 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/ijch.201700094" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/ijch.201700094</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ijch.201700094" target="_blank" >10.1002/ijch.201700094</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Cucurbit[n]urils-related Multitopic Supramolecular Components: Design, Properties, and Perspectives

Popis výsledku v původním jazyce

ucurbit[n]urils (CBns) are an intriguing family of macrocyclic hosts whose chemistry has undergone rapid developments in recent decades. The initial interest in the synthesis, modifications and binding properties has shifted to areas focused on applications in drug storage, delivery, and release, external-stimuli responsive devices, and molecular nano-reactors. Since CBns are fruitfully complemented by cyclodextrins (CDs) in such systems, guest molecules that contain several binding sites are needed. These multitopic guests provide not only a scaffold for holding CBns and CDs together in appropriate arrangements but also allow for manipulation with supramolecular aggregates, e.g., reorganization or release of macrocycles. In this review, we summarize recent studies related to the design of multitopic guests. Binding motifs properties, the role of attractive or repulsive lateral interactions, the competition-compensation effect, and rotaxane versus pseudorotaxane manner are discussed.

Název v anglickém jazyce

Cucurbit[n]urils-related Multitopic Supramolecular Components: Design, Properties, and Perspectives

Popis výsledku anglicky

ucurbit[n]urils (CBns) are an intriguing family of macrocyclic hosts whose chemistry has undergone rapid developments in recent decades. The initial interest in the synthesis, modifications and binding properties has shifted to areas focused on applications in drug storage, delivery, and release, external-stimuli responsive devices, and molecular nano-reactors. Since CBns are fruitfully complemented by cyclodextrins (CDs) in such systems, guest molecules that contain several binding sites are needed. These multitopic guests provide not only a scaffold for holding CBns and CDs together in appropriate arrangements but also allow for manipulation with supramolecular aggregates, e.g., reorganization or release of macrocycles. In this review, we summarize recent studies related to the design of multitopic guests. Binding motifs properties, the role of attractive or repulsive lateral interactions, the competition-compensation effect, and rotaxane versus pseudorotaxane manner are discussed.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Israel Journal of Chemistry

ISSN

0021-2148

e-ISSN

—

Svazek periodika

58

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

215-224

Kód UT WoS článku

000430466900004

EID výsledku v databázi Scopus

2-s2.0-85033799741