Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28140%2F14%3A43871536" target="_blank" >RIV/70883521:28140/14:43871536 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/70883521:28110/14:43871536

Výsledek na webu

<a href="http://www.electrochemsci.org/papers/vol9/91206910.pdf" target="_blank" >http://www.electrochemsci.org/papers/vol9/91206910.pdf</a>

DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis

Popis výsledku v původním jazyce

In this study, potential sweep technique and controlled potential electrolysis were used to analyze the electrochemical oxidation of glycerin in a three electrode system using platinum as a working electrode. Electrochemical experiments were performed atdifferent concentrations of glycerin and manganese dioxide (0.015-0.124 M) to analyze the reaction order of reactant and oxidant.Voltammograms were studied at different positive and negative potential limits (-1.5 to 1.5 V vs Ag/AgCl), sweep rates (0.01to 0.08 V/s) and temperatures (27 to 60 °C). The influence of each parameter on the voltammogram shape is discussed. Prolonged electrolysis at controlled potential yield glyceraldehyde, glyceric acid and glycolid acid as the main products.

Název v anglickém jazyce

Electrooxidation of Glycerin by Potential Sweep Technique and Controlled Potential Electrolysis

Popis výsledku anglicky

In this study, potential sweep technique and controlled potential electrolysis were used to analyze the electrochemical oxidation of glycerin in a three electrode system using platinum as a working electrode. Electrochemical experiments were performed atdifferent concentrations of glycerin and manganese dioxide (0.015-0.124 M) to analyze the reaction order of reactant and oxidant.Voltammograms were studied at different positive and negative potential limits (-1.5 to 1.5 V vs Ag/AgCl), sweep rates (0.01to 0.08 V/s) and temperatures (27 to 60 °C). The influence of each parameter on the voltammogram shape is discussed. Prolonged electrolysis at controlled potential yield glyceraldehyde, glyceric acid and glycolid acid as the main products.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CG - Elektrochemie

OECD FORD obor

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Projekt

<a href="/cs/project/ED2.1.00%2F03.0089" target="_blank" >ED2.1.00/03.0089: Centrum bezpečnostních, informačních a pokročilých technologií (CEBIA-Tech)</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

International Journal of Electrochemical Sciences

ISSN

1452-3981

e-ISSN

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Svazek periodika

2014

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

RS - Srbská republika

Počet stran výsledku

14

Strana od-do

6910 - 6923

Kód UT WoS článku

000345261900019

EID výsledku v databázi Scopus

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