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85 597 (0,128s)

Výsledek výzkumu

Model synthesis of six-membered carbocyclic spironucleosides

by Bucherer?Bergs reaction. On saturated substrates the reaction proceeded smoothly. On ?,?-unsaturated ketones, however, the Bucherer?Bergs reaction competed with Michael addition of cyanide ion. We showed that t...

CC - Organická chemie

  • 2010
  • Jx
Výsledek výzkumu

Solvent-free, catalyst-free aza-Michael addition of cyclohexylamine to diethyl maleate: reaction mechanism and kinetics

The aza-Michael reaction is the addition of an amine to an electron deficient C=C double bond. This reaction is also used in the synthesis of precursors the occurrence of three simultaneous reactions: (i) the aza-M...

Polymer science

  • 2018
  • Jimp
  • Odkaz
Výsledek výzkumu

Regioselectivity of radical addition reactions of ethers to methyl trifluoroacrylate in synthesis of 2-buten-4-olides

Regioselectivity in the title addition reactions is studied.

CC - Organická chemie

  • 2000
  • A
Výsledek výzkumu

Radical addition reactions of fluorinated species: new and novel effects, access to biocompatible substances and materials

Application of radical addition reactions to syntheses of biocompatible materials is discussed.

CC - Organická chemie

  • 2000
  • A
Výsledek výzkumu

Novel Addition Reactions of 2,2,7,7-Tetramethyl-3,5-octadiyne to the Methyl Groups of a Pentamethylcyclopentadienyl Ligand

A novel addition reaction across activated methyl groups of a pentamethylcyclopentadienyl ligand in titanocene complexes is described....

CA - Anorganická chemie

  • 1999
  • Jx
Výsledek výzkumu

Oxidative Catalysis Using the Stoichiometric Oxidant as a Reagent: An Efficient Strategy for Single-Electron-Transfer-Induced Tandem Anion-Radical Reactions

Oxidative single-electron transfer-catalyzed tandem reactions consisting of a conjugate addition and a radical cyclization are reported, which incorporate the mandatory terminal oxidant as a functionality into the product....

CC - Organická chemie

  • 2014
  • Jx
  • Odkaz
Výsledek výzkumu

Influence of intramolecular addition reactions to steam-cracking products distribution

In this paper, an influence of intramolecular addition on the steam-cracking products distribution was investigated a mechanistic model of steam cracking with automated generation of reaction network. As it was found, this type of c...

CI - Průmyslová chemie a chemické inženýrství

  • 2014
  • D
  • Odkaz
Výsledek výzkumu

Gold-Gold Cooperation in the Addition of Methanol to Alkynes

the addition of the methoxy group to the C-C triple bond. The kinetics of the reaction of a gold-catalyzed addition of methanol to alkynes, which shook the conception of gold as an inert metal. Here, we present a mechanism...

CC - Organická chemie

  • 2012
  • Jx
  • Odkaz
Výsledek výzkumu

Influence of intramolecular addition reactions on steam-cracking product distribution

Contribution is focused at an improvement of steam-crcking mechanistic model using reaction network generation (RNG). By including intramolecular radical addition reaction (radical cyclization) a significantly more accuract...

CI - Průmyslová chemie a chemické inženýrství

  • 2014
  • D
  • Odkaz
Výsledek výzkumu

Reaction Force Analysis of Solvent Effects in the Addition of HCl to Propene

We have investigated computationally, via reaction force analyses, the addition of the activation energies that are defined by the minimum of the reaction force for each of the reaction (prior to the reaction

BJ - Termodynamika

  • 2009
  • Jx
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