Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with Arylacetylenes into Fluorescent Polyacetylene-Type Conjugated Polymers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10315406" target="_blank" >RIV/00216208:11310/15:10315406 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/macp.201500240" target="_blank" >http://dx.doi.org/10.1002/macp.201500240</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/macp.201500240" target="_blank" >10.1002/macp.201500240</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with Arylacetylenes into Fluorescent Polyacetylene-Type Conjugated Polymers

Popis výsledku v původním jazyce

N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide (PNPr), i.e., the monomer with a terminal ethynyl group and 1,8-naphthalimide fluorophore, has been successfully copolymerized with a series of monoethynylarenes into well-soluble high-molecular-weight (M-w up to 210 000) linear polyacetylene-type copolymers containing from 14 to 51 mol% units derived from PNPr. The copolymerization of PNPr with bifunctional 4,4'-diethynylbiphenyl provides polyacetylene-type micro/mesoporous fluorescent network containing 8 mol% PNPr units and exhibiting the Brunauer-Emmett-Teller surface of approximate to 1000 m(2) g(-1). The copolymerizations (catalyzed with acetylacetonato(norborna-2,5-diene)rhodium complex, [Rh(nbd)acac]) proceed smoothly despite the fact that the homopolymerization of PNPr fails. The fluorescence of PNPr (emission at approximate to 510 nm) has been retained after the incorporation of PNPr into the copolymers. The fluorescence of the copolymers can be induced by a direct exc

Název v anglickém jazyce

Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with Arylacetylenes into Fluorescent Polyacetylene-Type Conjugated Polymers

Popis výsledku anglicky

N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide (PNPr), i.e., the monomer with a terminal ethynyl group and 1,8-naphthalimide fluorophore, has been successfully copolymerized with a series of monoethynylarenes into well-soluble high-molecular-weight (M-w up to 210 000) linear polyacetylene-type copolymers containing from 14 to 51 mol% units derived from PNPr. The copolymerization of PNPr with bifunctional 4,4'-diethynylbiphenyl provides polyacetylene-type micro/mesoporous fluorescent network containing 8 mol% PNPr units and exhibiting the Brunauer-Emmett-Teller surface of approximate to 1000 m(2) g(-1). The copolymerizations (catalyzed with acetylacetonato(norborna-2,5-diene)rhodium complex, [Rh(nbd)acac]) proceed smoothly despite the fact that the homopolymerization of PNPr fails. The fluorescence of PNPr (emission at approximate to 510 nm) has been retained after the incorporation of PNPr into the copolymers. The fluorescence of the copolymers can be induced by a direct exc

Druh

O - Ostatní výsledky

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA15-09637S" target="_blank" >GA15-09637S: Nové porézní materiály na bázi sítí konjugovaných polymerů obsahujících permanentní a konstitučně dynamické (reverzibilně uvolnitelné) příčné spojky</a><br>

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů