Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with arylacetylenes into fluorescent polyacetylene-type conjugated polymers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00445343" target="_blank" >RIV/61389013:_____/15:00445343 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/macp.201500240" target="_blank" >http://dx.doi.org/10.1002/macp.201500240</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/macp.201500240" target="_blank" >10.1002/macp.201500240</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with arylacetylenes into fluorescent polyacetylene-type conjugated polymers

Popis výsledku v původním jazyce

N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide (PNPr), i.e., the monomer with a terminal ethynyl group and 1,8-naphthalimide fluorophore, has been successfully copolymerized with a series of monoethynylarenes into well-soluble high-molecular-weight (Mw up to 210 000) linear polyacetylene-type copolymers containing from 14 to 51 mol% units derived from PNPr. The copolymerization of PNPr with bifunctional 4,4-diethynylbiphenyl provides polyacetylene-type micro/mesoporous fluorescent network containing 8 mol% PNPr units and exhibiting the Brunauer?Emmett?Teller surface of 1000 m2 g1. The copolymerizations (catalyzed with acetylacetonato(norborna-2,5-diene)rhodium complex, [Rh(nbd)acac]) proceed smoothly despite the fact that the homopolymerization of PNPr fails. The fluorescence of PNPr (emission at 510 nm) has been retained after the incorporation of PNPr into the copolymers. The fluorescence of the copolymers can be induced by a direct excitation of PNPr units or via an energ

Název v anglickém jazyce

Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with arylacetylenes into fluorescent polyacetylene-type conjugated polymers

Popis výsledku anglicky

N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide (PNPr), i.e., the monomer with a terminal ethynyl group and 1,8-naphthalimide fluorophore, has been successfully copolymerized with a series of monoethynylarenes into well-soluble high-molecular-weight (Mw up to 210 000) linear polyacetylene-type copolymers containing from 14 to 51 mol% units derived from PNPr. The copolymerization of PNPr with bifunctional 4,4-diethynylbiphenyl provides polyacetylene-type micro/mesoporous fluorescent network containing 8 mol% PNPr units and exhibiting the Brunauer?Emmett?Teller surface of 1000 m2 g1. The copolymerizations (catalyzed with acetylacetonato(norborna-2,5-diene)rhodium complex, [Rh(nbd)acac]) proceed smoothly despite the fact that the homopolymerization of PNPr fails. The fluorescence of PNPr (emission at 510 nm) has been retained after the incorporation of PNPr into the copolymers. The fluorescence of the copolymers can be induced by a direct excitation of PNPr units or via an energ

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Macromolecular Chemistry and Physics

ISSN

1022-1352

e-ISSN

—

Svazek periodika

216

Číslo periodika v rámci svazku

21

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

14

Strana od-do

2115-2128

Kód UT WoS článku

000364340200006

EID výsledku v databázi Scopus

2-s2.0-84946482956