Interface Engineering between the Metal-Organic Framework Nanocrystal and Graphene toward Ultrahigh Potassium-Ion Storage Performance
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10419525" target="_blank" >RIV/00216208:11310/20:10419525 - isvavai.cz</a>
Výsledek na webu
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=cWzeol4qeT" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=cWzeol4qeT</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsnano.0c03488" target="_blank" >10.1021/acsnano.0c03488</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Interface Engineering between the Metal-Organic Framework Nanocrystal and Graphene toward Ultrahigh Potassium-Ion Storage Performance
Popis výsledku v původním jazyce
The potassium-ion battery (PIB) has been recognized as a promising low-cost and high-energy battery; however, it suffers from a relatively low capacity and inferior cycling performance compared with current electrode materials. Herein, we report an effective interface engineering strategy to prepare metal-organic framework (MOF) nanocrystals tightly encapsulated by reduced graphene oxide (rGO) via strong chemical interaction as a free-standing anode for PIB. Based on experimental analysis and theoretical calculations, we systematically investigated the effect of the chemical-bonded interface between MOF nanocrystals and conductive rGO and revealed that the strong chemical interface can substantially enhance the adsorption energy and ion transport kinetics of the potassium ion within the MOF nanocrystals compared to the physical mixture of MOF and rGO with almost the same microscopic morphologies. As a result, such an MOF-rGO hybrid with strong interfacial chemical couplings delivered an ultrahigh reversible capacity of 422 mAh g(-1) at 0.1 A g(-1), superior rate performance (202 mAh g(-1) at 5 A g(-1)), and outstanding long-term cycling performance (an ultralow decay rate of 0.013% per cycle after 2000 cycles at 2 A g(-1)), which are not only significantly better than those of the physical mixture of MOF/rGO but also among the best for anodes for PIB reported thus far.
Název v anglickém jazyce
Interface Engineering between the Metal-Organic Framework Nanocrystal and Graphene toward Ultrahigh Potassium-Ion Storage Performance
Popis výsledku anglicky
The potassium-ion battery (PIB) has been recognized as a promising low-cost and high-energy battery; however, it suffers from a relatively low capacity and inferior cycling performance compared with current electrode materials. Herein, we report an effective interface engineering strategy to prepare metal-organic framework (MOF) nanocrystals tightly encapsulated by reduced graphene oxide (rGO) via strong chemical interaction as a free-standing anode for PIB. Based on experimental analysis and theoretical calculations, we systematically investigated the effect of the chemical-bonded interface between MOF nanocrystals and conductive rGO and revealed that the strong chemical interface can substantially enhance the adsorption energy and ion transport kinetics of the potassium ion within the MOF nanocrystals compared to the physical mixture of MOF and rGO with almost the same microscopic morphologies. As a result, such an MOF-rGO hybrid with strong interfacial chemical couplings delivered an ultrahigh reversible capacity of 422 mAh g(-1) at 0.1 A g(-1), superior rate performance (202 mAh g(-1) at 5 A g(-1)), and outstanding long-term cycling performance (an ultralow decay rate of 0.013% per cycle after 2000 cycles at 2 A g(-1)), which are not only significantly better than those of the physical mixture of MOF/rGO but also among the best for anodes for PIB reported thus far.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10403 - Physical chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2020
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
ACS Nano
ISSN
1936-0851
e-ISSN
—
Svazek periodika
14
Číslo periodika v rámci svazku
8
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
9
Strana od-do
10210-10218
Kód UT WoS článku
000566341000080
EID výsledku v databázi Scopus
2-s2.0-85090077522