Accelerated recrystallization of nanocrystalline films as a manifestation of the inner size effect of the diffusion coefficient

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F24%3A00012361" target="_blank" >RIV/46747885:24620/24:00012361 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0042207X24003956?via%3Dihub#fig3" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0042207X24003956?via%3Dihub#fig3</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.vacuum.2024.113349" target="_blank" >10.1016/j.vacuum.2024.113349</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Accelerated recrystallization of nanocrystalline films as a manifestation of the inner size effect of the diffusion coefficient

Popis výsledku v původním jazyce

The work is devoted to the study of recrystallization occurring during short-term annealing of 100 nm thick polycrystalline films of copper and silver. It is found that in copper films deposited by the method of thermal evaporation onto a substrate at room temperature, a bimodal crystallite size distribution with maxima at 15 and 35 nm is observed. The bimodal distribution in copper films is preserved during annealing, which leads to a shift of both peaks of the crystallite size distribution histograms to the larger sizes region. In contrast to Cu, even in as-deposited Ag films, besides the nanosized fraction, micron-sized crystallites are present. Apparently, these grains are formed due to the phenomenon of self-annealing and weakly evolve during heating owing to grain growth stagnation. The nanosized fraction in as-deposited Ag films is represented by crystallites with the most probable size of 25 nm, which increases to 50 nm as a result of short-term annealing at the temperature of 250°C. The grain-boundary diffusion coefficient was determined, which is more than 10-18 m2/s for both films of metals. The obtained value indicates a multiple intensification of self-diffusion processes in films, the thickness of which allows us to refer them to macroscopic sample

Název v anglickém jazyce

Accelerated recrystallization of nanocrystalline films as a manifestation of the inner size effect of the diffusion coefficient

Popis výsledku anglicky

The work is devoted to the study of recrystallization occurring during short-term annealing of 100 nm thick polycrystalline films of copper and silver. It is found that in copper films deposited by the method of thermal evaporation onto a substrate at room temperature, a bimodal crystallite size distribution with maxima at 15 and 35 nm is observed. The bimodal distribution in copper films is preserved during annealing, which leads to a shift of both peaks of the crystallite size distribution histograms to the larger sizes region. In contrast to Cu, even in as-deposited Ag films, besides the nanosized fraction, micron-sized crystallites are present. Apparently, these grains are formed due to the phenomenon of self-annealing and weakly evolve during heating owing to grain growth stagnation. The nanosized fraction in as-deposited Ag films is represented by crystallites with the most probable size of 25 nm, which increases to 50 nm as a result of short-term annealing at the temperature of 250°C. The grain-boundary diffusion coefficient was determined, which is more than 10-18 m2/s for both films of metals. The obtained value indicates a multiple intensification of self-diffusion processes in films, the thickness of which allows us to refer them to macroscopic sample

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20500 - Materials engineering

Projekt

—

Návaznosti

R - Projekt Ramcoveho programu EK

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Vacuum

ISSN

0042-207X

e-ISSN

—

Svazek periodika

226

Číslo periodika v rámci svazku

August

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

—

Kód UT WoS článku

001250107400001

EID výsledku v databázi Scopus

2-s2.0-85194875032