Surface and interface engineering in CO2-philic based UiO-66-NH2-PEI mixed matrix membranes via covalently bridging PVP for effective hydrogen purification

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12520%2F21%3A43902512" target="_blank" >RIV/60076658:12520/21:43902512 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22310/21:43923348 RIV/60461373:22340/21:43923348

Výsledek na webu

<a href="https://doi.org/10.1016/j.ijhydene.2020.11.081" target="_blank" >https://doi.org/10.1016/j.ijhydene.2020.11.081</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ijhydene.2020.11.081" target="_blank" >10.1016/j.ijhydene.2020.11.081</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Surface and interface engineering in CO2-philic based UiO-66-NH2-PEI mixed matrix membranes via covalently bridging PVP for effective hydrogen purification

Popis výsledku v původním jazyce

We report on the fabrication of the defect-free mixed-matrix membrane (MMM) based on the polyethylenimine (PEI) matrix with uniformly dispersed metal-organic framework (MOF) filler UiO-66-NH2, covalently bonded by polyvinylpyrrolidone (PVP). The key feature of the molecular level-controlled filler deposition in prepared UiO-66-NH2-PVP-PEI membranes was bridging the MOF particles to the PEI polymer matrix via PVP polymer chains. Such an approach improved the polymer-filler interface interactions and boosted the MOF dispersion into the polymer matrix for higher MOF loadings up to 23 wt %. The overall membrane structure and properties were characterized using FTIR, XRD, TG, DSC, SEM and 3D optical profiler techniques. Obtained results revealed the uniform dispersion of UiO-66-NH2, the strong polymer-filler interface interactions and entanglement of PEI with UiO-66-NH2-PVP. Furthermore, the outstanding CO2/H-2 separation performance was determined for the UiO-66-NH2-PVP-PEI membrane with 18 wt % of MOF loading; the average CO2 permeability of 394 Barrer and the separation factor of 12 for circa 100 h of the membrane testing overcome the 2008 Robeson reverse upper bound limit. Such improved CO2/H-2 separation performance was achieved due to the combination of the diffusion-solution mechanism with the preferential adsorption of the CO2 via the reversible bicarbonate reaction with amino groups of the UiO-66-NH2 and PEI which acts as fixed CO2 carrier sites in MMM structure. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Název v anglickém jazyce

Surface and interface engineering in CO2-philic based UiO-66-NH2-PEI mixed matrix membranes via covalently bridging PVP for effective hydrogen purification

Popis výsledku anglicky

We report on the fabrication of the defect-free mixed-matrix membrane (MMM) based on the polyethylenimine (PEI) matrix with uniformly dispersed metal-organic framework (MOF) filler UiO-66-NH2, covalently bonded by polyvinylpyrrolidone (PVP). The key feature of the molecular level-controlled filler deposition in prepared UiO-66-NH2-PVP-PEI membranes was bridging the MOF particles to the PEI polymer matrix via PVP polymer chains. Such an approach improved the polymer-filler interface interactions and boosted the MOF dispersion into the polymer matrix for higher MOF loadings up to 23 wt %. The overall membrane structure and properties were characterized using FTIR, XRD, TG, DSC, SEM and 3D optical profiler techniques. Obtained results revealed the uniform dispersion of UiO-66-NH2, the strong polymer-filler interface interactions and entanglement of PEI with UiO-66-NH2-PVP. Furthermore, the outstanding CO2/H-2 separation performance was determined for the UiO-66-NH2-PVP-PEI membrane with 18 wt % of MOF loading; the average CO2 permeability of 394 Barrer and the separation factor of 12 for circa 100 h of the membrane testing overcome the 2008 Robeson reverse upper bound limit. Such improved CO2/H-2 separation performance was achieved due to the combination of the diffusion-solution mechanism with the preferential adsorption of the CO2 via the reversible bicarbonate reaction with amino groups of the UiO-66-NH2 and PEI which acts as fixed CO2 carrier sites in MMM structure. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GA19-14547S" target="_blank" >GA19-14547S: Nové kompozitní membrány pro cílené separace plynů a par (CoMeTS)</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

International Journal of Hydrogen Energy

ISSN

0360-3199

e-ISSN

—

Svazek periodika

46

Číslo periodika v rámci svazku

7

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

5449-5458

Kód UT WoS článku

000608630000015

EID výsledku v databázi Scopus

2-s2.0-85097478668