Determination of Water content in Pyrolytic Tars Using Coulometric KArl-Fischer Titration

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22320%2F17%3A43903786" target="_blank" >RIV/60461373:22320/17:43903786 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Determination of Water content in Pyrolytic Tars Using Coulometric KArl-Fischer Titration

Popis výsledku v původním jazyce

The liquid organic fraction of pyrolytic tar has a high energy value which makes possible its utilization as an energy source. However, before utilization, it is crucial to remove water from the liquid fraction. The presence of water reduces the energy value of pyrolytic tars. Water separation from the organic tar fraction is a complex process, since an emulsion can be readily formed. Therefore, after phase separation, it is important to know the residual water content in the organic phase and whether it is necessary to further dry it. The results presented in this manuscript focus on a water determination in liquid products from coal and biomass pyrolysis by a coulometric Karl-Fischer titration. The Coulometric Karl-Fischer titration is often used for a water content determination in gaseous, liquid and solid samples. However, to date, this titration method has not been used for a water determination in tars. A new water determination method, which has been tested on different types of tar, has been developed. The Coulometric Karl-Fischer titration is suitable for tar samples with a water content not greater than 5 wt%. The obtained experimental results indicate that the new introduced method can be used with a very good repeatability for a water content determination in tars.

Název v anglickém jazyce

Determination of Water content in Pyrolytic Tars Using Coulometric KArl-Fischer Titration

Popis výsledku anglicky

The liquid organic fraction of pyrolytic tar has a high energy value which makes possible its utilization as an energy source. However, before utilization, it is crucial to remove water from the liquid fraction. The presence of water reduces the energy value of pyrolytic tars. Water separation from the organic tar fraction is a complex process, since an emulsion can be readily formed. Therefore, after phase separation, it is important to know the residual water content in the organic phase and whether it is necessary to further dry it. The results presented in this manuscript focus on a water determination in liquid products from coal and biomass pyrolysis by a coulometric Karl-Fischer titration. The Coulometric Karl-Fischer titration is often used for a water content determination in gaseous, liquid and solid samples. However, to date, this titration method has not been used for a water determination in tars. A new water determination method, which has been tested on different types of tar, has been developed. The Coulometric Karl-Fischer titration is suitable for tar samples with a water content not greater than 5 wt%. The obtained experimental results indicate that the new introduced method can be used with a very good repeatability for a water content determination in tars.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

20704 - Energy and fuels

Projekt

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Návaznosti

V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Acta Polytechnica, Journal of Advanced Engineering

ISSN

1210-2709

e-ISSN

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Svazek periodika

57

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

CZ - Česká republika

Počet stran výsledku

6

Strana od-do

8-13

Kód UT WoS článku

000411586100002

EID výsledku v databázi Scopus

2-s2.0-85014534080