Dataset for electrochemical oxidation of triticonazole published in Electrochemical Oxidation of Triticonazole on Boron-Doped Diamond-Based Electrodes for Analysis of Real Matrices

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F26%3A00647164" target="_blank" >RIV/61388955:_____/26:00647164 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Dataset for electrochemical oxidation of triticonazole published in Electrochemical Oxidation of Triticonazole on Boron-Doped Diamond-Based Electrodes for Analysis of Real Matrices

Popis výsledku v původním jazyce

The voltammetric behavior of the triazole fungicide triticonazole (TTC) was investigated for the first time using a boron-doped diamond electrode (BDDE). TTC showed an irreversible oxidation peak at +1.5 V, a weak second oxidation near +2.0 V, and a reduction peak around 0 V (vs. Ag/AgCl/KCl, sat.). The oxidation mechanism was proposed based on electrochemical experiments, theoretical calculations, and LC/MS analysis after exhaustive electrolysis. A square-wave voltammetric method was developed with a detection limit of 0.125 µmol L⁻¹ and a linear range of 0.5–20 µmol L⁻¹. For natural waters, solid-phase extraction preconcentration was applied. The method was successfully transferred to screen-printed BDDE sensors, extending the linear range to 0.25–60 µmol L⁻¹ and improving sensitivity by 1.68–1.85×.

Název v anglickém jazyce

Dataset for electrochemical oxidation of triticonazole published in Electrochemical Oxidation of Triticonazole on Boron-Doped Diamond-Based Electrodes for Analysis of Real Matrices

Popis výsledku anglicky

The voltammetric behavior of the triazole fungicide triticonazole (TTC) was investigated for the first time using a boron-doped diamond electrode (BDDE). TTC showed an irreversible oxidation peak at +1.5 V, a weak second oxidation near +2.0 V, and a reduction peak around 0 V (vs. Ag/AgCl/KCl, sat.). The oxidation mechanism was proposed based on electrochemical experiments, theoretical calculations, and LC/MS analysis after exhaustive electrolysis. A square-wave voltammetric method was developed with a detection limit of 0.125 µmol L⁻¹ and a linear range of 0.5–20 µmol L⁻¹. For natural waters, solid-phase extraction preconcentration was applied. The method was successfully transferred to screen-printed BDDE sensors, extending the linear range to 0.25–60 µmol L⁻¹ and improving sensitivity by 1.68–1.85×.

Druh

X - Nezařazeno

CEP obor

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OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/EH22_008%2F0004558" target="_blank" >EH22_008/0004558: Pokročilé víceškálové materiály pro nosné klíčové technologie</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2026

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů