Metal Complexes with Very Large Dipole Moments: the Anionic Carborane Nitriles 12-NC-CB11X11- (X = H, F, CH3) as Ligands on Pt(II) and Pd(II)

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F16%3A00460822" target="_blank" >RIV/61388963:_____/16:00460822 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/00216208:11310/16:10324337
Výsledek na webu
<a href="http://dx.doi.org/10.1021/acs.inorgchem.5b02678" target="_blank" >http://dx.doi.org/10.1021/acs.inorgchem.5b02678</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.5b02678" target="_blank" >10.1021/acs.inorgchem.5b02678</a>

Jazyk výsledku
angličtina
Název v původním jazyce
Metal Complexes with Very Large Dipole Moments: the Anionic Carborane Nitriles 12-NC-CB11X11- (X = H, F, CH3) as Ligands on Pt(II) and Pd(II)
Popis výsledku v původním jazyce
The anionic nitriles 1-R-12-NC-CB11H10- (R = H, CH3, I, COOH), 12-NC-1-H-CB11/Me-10(-), and 12-NC-1-H-CB11F10- were prepared, and three of them were examined for complex formation with (Et3P)(2)Pt(II) and (Et3P)(2)Pd(II). Several stable internally charge-compensated zwitterionic complexes were obtained and characterized. RI-BP86/SV(P) calculations suggest that their dipole moments exceed 20 D. An attempt to measure the dipole moments in solution failed due to insufficient solubility in solvents of low polarity.
Název v anglickém jazyce
Metal Complexes with Very Large Dipole Moments: the Anionic Carborane Nitriles 12-NC-CB11X11- (X = H, F, CH3) as Ligands on Pt(II) and Pd(II)
Popis výsledku anglicky
The anionic nitriles 1-R-12-NC-CB11H10- (R = H, CH3, I, COOH), 12-NC-1-H-CB11/Me-10(-), and 12-NC-1-H-CB11F10- were prepared, and three of them were examined for complex formation with (Et3P)(2)Pt(II) and (Et3P)(2)Pd(II). Several stable internally charge-compensated zwitterionic complexes were obtained and characterized. RI-BP86/SV(P) calculations suggest that their dipole moments exceed 20 D. An attempt to measure the dipole moments in solution failed due to insufficient solubility in solvents of low polarity.

Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CA - Anorganická chemie
OECD FORD obor
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Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění
2016
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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