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Cobalt-entrenched N-, O-, and S-tridoped carbons as efficient multifunctional sustainable catalysts for base-free selective oxidative esterification of alcohols

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F18%3A73587887" target="_blank" >RIV/61989592:15310/18:73587887 - isvavai.cz</a>

  • Výsledek na webu

    <a href="http://pubs.rsc.org/en/content/articlepdf/2018/gc/c8gc01333k" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2018/gc/c8gc01333k</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c8gc01333k" target="_blank" >10.1039/c8gc01333k</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Cobalt-entrenched N-, O-, and S-tridoped carbons as efficient multifunctional sustainable catalysts for base-free selective oxidative esterification of alcohols

  • Popis výsledku v původním jazyce

    We report the synthesis of sustainable and reusable non-noble transition-metal (cobalt) nanocatalysts containing N-, O-, and S-tridoped carbon nanotube (Co@NOSC) composites. The expensive and benign carrageenan served as the source of carbon, oxygen, and sulfur, whereas urea served as the nitrogen source. The material was prepared via direct mixing of precursors and freeze-drying followed by carbonization under nitrogen at 900 degrees C. Co@NOSC catalysts comprising a Co inner core and outer electron-rich heteroatom-doped carbon shell were thoroughly characterized using various techniques, namely, TEM, HRTEM, STEM elemental mapping, XPS, BET, and ICP-MS. The utility of the Co@NOSC catalyst was explored for base-free selective oxidative esterification of alcohols to the corresponding esters under mild reaction conditions; excellent conversions (up to 97%) and selectivities (up to 99%) were discerned. Furthermore, the substrate scope was explored for the cross-esterification of benzyl alcohol with long-chain alcohols (up to 98%) and lactonization of diols (up to 68%). The heterogeneous nature and stability of the catalyst facilitated by its ease of separation for long-term performance and recycling studies showed that the catalyst was robust and remained active even after six recycling experiments. EPR measurements were performed to deduce the reaction mechanism in the presence of POBN (alpha-(4-pyridyl-1-oxide)-N-tert-butylnitrone) as a spin-trapping agent, which confirmed the formation of (CH2OH)-C-center dot radicals and H-center dot radicals, wherein the solvent plays an active role in a nonconventional manner. A plausible mechanism was proposed for the oxidative esterification of alcohols on the basis of EPR findings. The presence of a cobalt core along with cobalt oxide and the electron-rich N-, O-, and S-doped carbon shell displayed synergistic effects to afford good to excellent yields of products

  • Název v anglickém jazyce

    Cobalt-entrenched N-, O-, and S-tridoped carbons as efficient multifunctional sustainable catalysts for base-free selective oxidative esterification of alcohols

  • Popis výsledku anglicky

    We report the synthesis of sustainable and reusable non-noble transition-metal (cobalt) nanocatalysts containing N-, O-, and S-tridoped carbon nanotube (Co@NOSC) composites. The expensive and benign carrageenan served as the source of carbon, oxygen, and sulfur, whereas urea served as the nitrogen source. The material was prepared via direct mixing of precursors and freeze-drying followed by carbonization under nitrogen at 900 degrees C. Co@NOSC catalysts comprising a Co inner core and outer electron-rich heteroatom-doped carbon shell were thoroughly characterized using various techniques, namely, TEM, HRTEM, STEM elemental mapping, XPS, BET, and ICP-MS. The utility of the Co@NOSC catalyst was explored for base-free selective oxidative esterification of alcohols to the corresponding esters under mild reaction conditions; excellent conversions (up to 97%) and selectivities (up to 99%) were discerned. Furthermore, the substrate scope was explored for the cross-esterification of benzyl alcohol with long-chain alcohols (up to 98%) and lactonization of diols (up to 68%). The heterogeneous nature and stability of the catalyst facilitated by its ease of separation for long-term performance and recycling studies showed that the catalyst was robust and remained active even after six recycling experiments. EPR measurements were performed to deduce the reaction mechanism in the presence of POBN (alpha-(4-pyridyl-1-oxide)-N-tert-butylnitrone) as a spin-trapping agent, which confirmed the formation of (CH2OH)-C-center dot radicals and H-center dot radicals, wherein the solvent plays an active role in a nonconventional manner. A plausible mechanism was proposed for the oxidative esterification of alcohols on the basis of EPR findings. The presence of a cobalt core along with cobalt oxide and the electron-rich N-, O-, and S-doped carbon shell displayed synergistic effects to afford good to excellent yields of products

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10403 - Physical chemistry

Návaznosti výsledku

  • Projekt

    Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Ostatní

  • Rok uplatnění

    2018

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    GREEN CHEMISTRY

  • ISSN

    1463-9262

  • e-ISSN

  • Svazek periodika

    20

  • Číslo periodika v rámci svazku

    15

  • Stát vydavatele periodika

    GB - Spojené království Velké Británie a Severního Irska

  • Počet stran výsledku

    15

  • Strana od-do

    3542-3556

  • Kód UT WoS článku

    000441581600014

  • EID výsledku v databázi Scopus

    2-s2.0-85050949665