Ageing of Mg-Ni-H hydrogen storage alloys
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F12%3A00380254" target="_blank" >RIV/68081723:_____/12:00380254 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.ijhydene.2012.07.049" target="_blank" >http://dx.doi.org/10.1016/j.ijhydene.2012.07.049</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijhydene.2012.07.049" target="_blank" >10.1016/j.ijhydene.2012.07.049</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Ageing of Mg-Ni-H hydrogen storage alloys
Popis výsledku v původním jazyce
In this work, ageing of Mg/Mg2Ni mixtures was investigated. It was observed that hydrogen desorption kinetics from hydrided Mg/Mg2Ni was improved considerably after ageing at room temperature for several days. The ageing was interpreted in terms of phasechanges. Even after almost complete hydridation, besides two main phases e MgH2 and Mg2NiH4 - a certain amount of Mg2NiH0.3 was always present. Similar as Mg2NiH4 phase, Mg2NiH0.3 islands were located on the surface of MgH2 grains. Mg2NiH0.3 transformedinto Mg2NiH4 at the expense of hydrogen from an adjoining MgH2 grain. In such a way, a clean double layer (Mg)eMg2NiH4 was formed, acting as a gate for easy hydrogen desorption from MgH2. It was found that the Mg2NiH4 phase was slightly enriched on non-twinned modification LT1 during the ageing. As a result, both the creation of (Mg)eMg2NiH4 desorption bridges and enrichment of Mg2NiH4 on LT1 during the ageing facilitated onset of rapid hydrogen desorption.
Název v anglickém jazyce
Ageing of Mg-Ni-H hydrogen storage alloys
Popis výsledku anglicky
In this work, ageing of Mg/Mg2Ni mixtures was investigated. It was observed that hydrogen desorption kinetics from hydrided Mg/Mg2Ni was improved considerably after ageing at room temperature for several days. The ageing was interpreted in terms of phasechanges. Even after almost complete hydridation, besides two main phases e MgH2 and Mg2NiH4 - a certain amount of Mg2NiH0.3 was always present. Similar as Mg2NiH4 phase, Mg2NiH0.3 islands were located on the surface of MgH2 grains. Mg2NiH0.3 transformedinto Mg2NiH4 at the expense of hydrogen from an adjoining MgH2 grain. In such a way, a clean double layer (Mg)eMg2NiH4 was formed, acting as a gate for easy hydrogen desorption from MgH2. It was found that the Mg2NiH4 phase was slightly enriched on non-twinned modification LT1 during the ageing. As a result, both the creation of (Mg)eMg2NiH4 desorption bridges and enrichment of Mg2NiH4 on LT1 during the ageing facilitated onset of rapid hydrogen desorption.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
JG - Hutnictví, kovové materiály
OECD FORD obor
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Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2012
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
International Journal of Hydrogen Energy
ISSN
0360-3199
e-ISSN
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Svazek periodika
37
Číslo periodika v rámci svazku
OCT
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
8
Strana od-do
14257-14264
Kód UT WoS článku
000309493600039
EID výsledku v databázi Scopus
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