Analysis of MCPD and Glycidyl Fatty Acid Esters in Refined Plant Oils by Supercritical Fluid ChromatographyHigh-Resolution Mass Spectrometry

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22330%2F22%3A43925030" target="_blank" >RIV/60461373:22330/22:43925030 - isvavai.cz</a>

Výsledek na webu

—

DOI - Digital Object Identifier

—

Jazyk výsledku

angličtina

Název v původním jazyce

Analysis of MCPD and Glycidyl Fatty Acid Esters in Refined Plant Oils by Supercritical Fluid ChromatographyHigh-Resolution Mass Spectrometry

Popis výsledku v původním jazyce

2- and 3-chloropropane-1,2-diol (2- and 3-MCPD) and their fatty acid esters (2- and 3-MCPDE) together with glycidyl fatty acids esters (GE) belong to a group of process-induced contaminants. They are formed in high temperature environments and most commonly occur in refined vegetable oils. With regards to the documented toxicity of free 3-MCPD (IARC group 2B) and glycidol (IARC group 2A), since 2021 maximum limits for GE and 3-MCPDE are enforceable in the European Union. Hence, the requirements for adequate analytical methods is constantly increasing.The aim of this study was to develop a method enabling a rapid, simultaneous determination of 9 3-MCPDE and 7 GE in vegetable oils and fats, with the use of supercritical fluid chromatography coupled with mass spectrometry (SFC-MS). Contrary to a routine GC-MS method the sample throughput was greatly increased. The recovery, repeatability and limits of quantification required by legislation were met for majority of analytes.

Název v anglickém jazyce

Analysis of MCPD and Glycidyl Fatty Acid Esters in Refined Plant Oils by Supercritical Fluid ChromatographyHigh-Resolution Mass Spectrometry

Popis výsledku anglicky

2- and 3-chloropropane-1,2-diol (2- and 3-MCPD) and their fatty acid esters (2- and 3-MCPDE) together with glycidyl fatty acids esters (GE) belong to a group of process-induced contaminants. They are formed in high temperature environments and most commonly occur in refined vegetable oils. With regards to the documented toxicity of free 3-MCPD (IARC group 2B) and glycidol (IARC group 2A), since 2021 maximum limits for GE and 3-MCPDE are enforceable in the European Union. Hence, the requirements for adequate analytical methods is constantly increasing.The aim of this study was to develop a method enabling a rapid, simultaneous determination of 9 3-MCPDE and 7 GE in vegetable oils and fats, with the use of supercritical fluid chromatography coupled with mass spectrometry (SFC-MS). Contrary to a routine GC-MS method the sample throughput was greatly increased. The recovery, repeatability and limits of quantification required by legislation were met for majority of analytes.

Druh

J_ost - Ostatní články v recenzovaných periodicích

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

LC GC Europe

ISSN

1471-6577

e-ISSN

—

Svazek periodika

35

Číslo periodika v rámci svazku

s7

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

7

Strana od-do

28-34

Kód UT WoS článku

—

EID výsledku v databázi Scopus

—